Pillared-layer MOF Based on Template-directed Method: Synthesis, Structure and Proton Conduction Properties  

作　　者：WANG Fu-Xiang REN Guo-Jian TIAN Rui-Jing FENG Li-Juan YANG Yong-Hang DENG Yong-Yan PAN Qin-He 

机构地区：[1]Key Laboratory of Advanced Materials of Tropical Island Resources,Ministry of Education,School of Science,Hainan University,Haikou 570228,China [2]School of Information Engineering,Changchun Sci-Tech University,Changchun 130600,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第7期1337-1342,共6页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China(21761010);Natural Science Foundation of Hainan Province(217055 and 217018);the Hainan University start-up fund(kyqd1654 and KYQD(ZR)1806);the Opening Project of Key Laboratory of Polyoxometalate Science of Ministry of Education。

摘　　要：By using Co(NH3)63+as the template,a new complex HNU-38 was synthesized under hydrothermal reaction through the adoption of H3BTC and Cl-as the ligands(H3BTC=1,3,5-benzenetricarboxylic acid).HNU-38 crystallized in the monoclinic system,P21/c space group with a=9.9696(3),b=17.0580(6),c=16.5263(6)?,β=100.400(2)o,Z=4,V=2764.31(16)?3,Mr=883.63,Dc=2.123 g/cm3,F(000)=1736,S=0.920,R=0.0358 and wR=0.0838(Ⅰ>2σ(Ⅰ)).In HNU-38,the Cd2+and BTC3-were linked together to form layers with Cl-serving as the pillar.It should be noted that(H2O)n chains were found in the channels and play a co-templating role along with the Co(NH3)63+cations in HNU-38,and the proton conduction properties were investigated.

关 键 词：TEMPLATE SYNTHESIS metal-organic framework pillared-layer proton conduction 

分 类 号：O641.4[理学—物理化学]