负载型钯催化剂用于氯代芳烃Suzuki交叉偶联反应的研究进展  

Research progress of supported palladium catalysts for Suzuki cross-coupling reaction of aryl chlorides

作　　者：唐勇 米末 金荣华 林静容 TANG Yong;MOHAMMED Abdulelah Taher Ali;JIN Ronghua;LIN Jingrong(College of Chemistry and Materials Science,Shanghai Normal University,Shanghai 200234,China)

机构地区：[1]上海师范大学化学与材料科学学院,上海200234

出　　处：《上海师范大学学报（自然科学版）》2020年第4期422-432,共11页Journal of Shanghai Normal University(Natural Sciences)

基　　金：国家自然科学基金(21872095)。

摘　　要：Suzuki交叉偶联反应是一类典型的形成碳-碳单键的反应,是以金属钯(Pd)为催化剂,卤代芳烃与有机硼酸化合物进行的交叉偶联反应.相对于传统仅用价廉易得的氯代芳烃化合物为反应原料的Suzuki交叉偶联反应,负载型Pd催化剂有着催化高效、分离简便、可重复使用等优点.简述了不同载体负载的Pd催化剂对于氯代芳烃的Suzuki交叉偶联反应的研究进展.The palladium(Pd)-catalyzed cross-coupling reaction between organic boricacids and aryl halides provides a powerful and general method for the formation of carbon-carbon bonds known as the Suzuki cross-coupling.It was found that with the cheap and commercially availablearyl chlorides as reactants,the supported Pd catalysts exhibited high efficiency,easy separation,and reusability.This review describes some research progresses of the supported Pd catalysts for Suzuki cross-coupling reaction of aryl chlorides.

关 键 词：负载型钯(Pd)催化剂 氯代芳烃 Suzuki交叉偶联 

分 类 号：TQ032.41[化学工程]