氧基氯化铁非均相活化过一硫酸盐降解金橙Ⅱ  

Degradation of AO7 by PMS activated by FeOCl.

作　　者：王柯晴 徐劼 陈家斌 王澜静 吴玮[1] WANG Ke-qing;XU Jie;CHEN Jia-bin;WANG Lan-jing;WU Wei(School of Environmental Sciences and Engineering,Suzhou University of Science and Technology,Suzhou 215009,China;School of Environmental Sciences and Engineering,Tongji University,Shanghai 200092,China)

机构地区：[1]苏州科技大学环境科学与工程学院,江苏苏州215009 [2]同济大学环境科学与工程学院,上海200092

出　　处：《中国环境科学》2020年第8期3385-3393,共9页China Environmental Science

基　　金：水体污染控制与治理科技重大专项(No.2017ZX07201001);国家自然科学基金资助项目(51778391).

摘　　要：采用部分热分解法制备了氧基氯化铁(FeOCl),用于活化过一硫酸盐(PMS)降解难降解偶氮染料金橙Ⅱ(AO7).利用X射线光电子能谱分析(XPS)、扫描电镜(SEM)和X射线衍射光谱(XRD)对其进行了表征;通过实验评估FeOCl/PMS体系对AO7的降解效果并分析了影响AO7去除率的各种因素.结果表明:FeOCl活化PMS降解AO7效果良好,矿化率达44%.在中性条件下,当FeOCl投加量50mg/L、PMS浓度1.0mmol/L、AO7浓度0.05mmol/L时,AO7可在30min内完全降解.随PMS投加量、FeOCl投加量、Cl-浓度和反应初始pH值的增大,AO7的脱色效果提高.FeOCl还具有良好的重复利用性.此外,通过自由基淬灭实验、EPR测试和XPS分析了反应的主要活性物种和反应机理:由PMS活化产生的SO4·-和·OH对污染物进行降解,其中主要活性物种为SO4·-.FeOCl was prepared by the partial thermal decomposition method,and then used to activate PMS to degrade refractory azo dye AO7.The synthesized FeOCl was characterized by XPS,SEM and XRD.The degradation of AO7 was evaluated in the FeOCl/PMS system,and various factors affecting the removal rate of AO7 was investigated.The results showed that AO7 was rapidly degraded in the FeOCl/PMS system,and mineralization rate has reached to 44%.AO7 could be completely degraded in 30min at neutral condition with 50mg/L FeOCl,1.0mmol/L PMS and 0.05mmol/L AO7.The decolorization of AO7 increased with the increase of PMS concentration,FeOCl dosage,Cl-concentration and the initial pH.FeOCl also exhibited a fine reusability.The main active species and reaction mechanism were verified by the radical quenching experiment,EPR test and XPS analysis.The SO4·-and·OH produced by the activation of PMS contributed to the degradation of pollutants,and SO4·-played the dominant role.

关 键 词：氧基氯化铁(FeOCl) 活化 金橙Ⅱ(AO7) 过一硫酸盐(PMS) 硫酸根自由基(SO4·-) 

分 类 号：X703[环境科学与工程—环境工程]