Two-dimensional Metal-Organic Frameworks and Derivatives for Electrocatalysis  

作　　者：WEN Jinguli LI Yuwen GAO Junkuo 

机构地区：[1]Institute of Functional Porous Materials,School of Materials Science and Engineering,Zhejiang Sci-Tech University,Hangzhou 310018,P.R.China

出　　处：《Chemical Research in Chinese Universities》2020年第4期662-679,共18页高等学校化学研究（英文版）

基　　金：Supported by the Zheiiang Provincial Natural Science Foundation,China(No.LY20E020001);the National Natural Science Foundation of China(Nos.51602301,51672251);the Fundamental Research Funds of Zhejiang Sci-Tech University,China(No.20190007)。

摘　　要：The most important topics in the world todav are environmental and resource issues.Ihe development of green and clean enerev is still one of the ereat challenges of social sustainable development.Two-dimensiona(2D)metal-organic frameworks(MOFs)and derivatives have exceptional potential as high-efhiciency electrocatalvsts for clean enerey technologies.This review summarizes various synthesis strategies and applications of 2D MOFs and derivatives in electrocatalysis.Firstly,we will outline the advantages and uniqueness of 2D MOFs and derivatives.as well as their applicable areas.Secondly,the svnthetic strategies of 2D MOFs and derivatives are briefly classified Fach category is summarized and we list classic representative fabrication methods,including specific fabrication methods and mechanisms,corresponding structural characteristics.and insights into the advantages and limitations of the svnthesis method.Thirdly,we separately classify and summarize the application of 2D MOFs and derivatives in electrocatalysis,including electrocatalytic water splitting,oxygen reduction reaction(ORR),CO reduction reaction(CO.RR),and other electrocatalvtic applications.Finally.the development prospects and existing challenges to 2D MOEs and derivatives are discussed.

关 键 词：TWO-DIMENSIONAL Metal-organic framework DERIVATIVE Synthesis strategy ELECTROCATALYSIS 

分 类 号：O64[理学—物理化学]