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作 者:翟明路 段浩楠 蒲彦锋 乔聪震 李磊[2] 肖亚辉 杨浩 ZHAI Minglu;DUAN Haonan;PU Yanfeng;QIAO Congzhen;LI Lei;XIAO Yahui;YANG Hao(Hleran Enginring Research Cexter of Resource&Energy Reovery from Waste,College of Chenistry and Chenical Enginring,Henan University,Kaifeng 475004,Henan,China;State Key Laboratory of Coal Conuersion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,Shanxi,China)
机构地区:[1]河南大学化学化工学院,河南省废弃物资源能源化工程技术研究中心,河南开封475004 [2]中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001
出 处:《化学研究》2020年第3期196-205,共10页Chemical Research
基 金:国家科技支撑计划(2013BAB11B02);河南大学博士后基金(FJ3050A0670001).
摘 要:随着全球能源消耗量的增长,传统化石燃料等不可再生能源将日趋枯竭且环境污染等弊端日益突显.利用绿色、可再生生物质资源,尤其是脂肪酸(酯)脱氧转化制备液体燃料已成为全球关注的热点.脂肪酸(酯)脱氧过程中氢源的不同,直接影响脱氧的反应路径、效率和成本.鉴于此,本文根据氢源的不同,综合分析了近年来脂肪酸(酯)的直接加氢脱氧、原位加氢脱氧、脱羧脱羰等过程的研究进展.提出了未来脱氧过程的主要发展方向和研究重点,为商业化脱氧技术的开发提供新的助力.With the growth of global energy consumption,non⁃renewable energy sources such as traditional fossil fuels will be gradually exhausted and environmental pollution and other drawbacks are becoming increasingly prominent.The deoxygenation of green and renewable biomass resources,especially fatty acids(esters),to produce liquid fuels has become a global hotpoint.The difference in hydrogen source during the deoxygenation of fatty acids(esters)directly affects the reaction path,efficiency and cost of deoxygenation.In view of this,the research progress of direct hydrodeaeration,in⁃situ hydrodeaeration,decarboxylation and decarbonylation of fatty acids(esters)was reviewed according to the different hydrogen sources.The main development direction and research emphasis of the future deoxygenation process were proposed to provide new assistance for the development of commercial deoxygenation technology.
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