双丙酮丙烯酰胺-丙烯酸酯共聚物基蓄能型发光涂料的制备  

Preparation of Energy Storage Luminescent Coatings Based on Diacetone Acrylamide-Acrylate Copolymer

作　　者：李庆博 赵奇 刘林生 徐艺璇 皮红[1] Qingbo Li;Qi Zhao;Linsheng Liu;Yixuan Xu;Hong Pi(Polymer Research Institute,State Key Laboratory of Polymer Materials Engineering,Sichuan.University,Chengdu 610065,China;TCL Electronic Holding Co.Ltd,Huizhou 516000,China)

机构地区：[1]四川大学高分子研究所高分子材料工程国家重点实验室(四川大学),四川成都610065 [2]TCL电子控股有限公司,广东惠州516000

出　　处：《高分子材料科学与工程》2020年第7期176-180,190,共6页Polymer Materials Science & Engineering

基　　金：宜宾天原集团股份有限公司资助项目。

摘　　要：以分子设计为基础,将可在室温进行交联的功能单元双丙酮丙烯酰胺引入丙烯酸酯聚合物中,制得了蓄能型发光涂料。该涂料在紫外光和可见光下可被有效激发,撤去光源后能持续发光,余辉时长可达12 h。涂料对聚氯乙烯(PVC)、聚苯乙烯(PS)、丙烯腈-丁二烯-苯乙烯三元共聚物(ABS)等塑料基材有很好的附着力,可制成塑基蓄能型涂层制品,拓展了蓄能型涂料的理论及应用研究领域。The energy storage luminescent coating was synthesized by inserting diacetone-acryloamide,which could be crosslinked at room temperature,into acrylate polymers.This coating could be excited effectively by ultraviolet or visible light.And the afterglow of the coating lasts up to 12 h.The coating has good adhesion to plastic substrates,such as PVC,PS,ABS and etc,indicating that it is very useful for research on energy storage luminescent coating both in theoretical and practical fields.

关 键 词：双丙酮丙烯酰胺 丙烯酸酯 蓄能型发光涂料 聚氯乙烯 聚苯乙烯 丙烯腈-丁二烯-苯乙烯三元共聚物 

分 类 号：TQ637.4[化学工程—精细化工]