两个镉配位聚合物的合成和晶体结构  

The Synthesis and Crystal Structure of Two Cadmium Coordination Polymers

作　　者：张剑 王梦蝶 王小峰[1] 谭春红[1] ZHANG Jian;WANG mengdie;WANG Xiaofeng;TANG Chunhong(School of Chemistry and Chemical Engineering,University of South China,Hengyang,Hunan 421001,China)

机构地区：[1]南华大学化学化工学院,湖南衡阳421001

出　　处：《南华大学学报（自然科学版）》2020年第4期80-84,共5页Journal of University of South China：Science and Technology

基　　金：湖南省教育厅一般项目(2017SJY27);南华大学博士科研启动基金项目(2015XQD11,2010XQD13)。

摘　　要：选用2,2-联吡啶和二羧酸配体,在溶剂热条件下与硝酸镉反应,制得配位聚合物Cd(FAC)(2,2-bpy)·H2On(1)和Cd(BDC)(2,2-bpy)·H2On(2)。对这两个配位聚合物进行X-射线单晶衍射、元素分析表征,结构分析表明配位聚合物1和2都是一维链状结构。Two new cadmium coordination polymers[Cd(FAC)(2,2-bpy)·H 2O]n(1),[Cd(BDC)(2,2-bpy)·H 2O]n(2)were successfully prepared under solvothermal reaction of fumaric acid(or terephthalic acid),2,2-bipyridine and cadmium nitrate in N,N′-dimethylformamide.The two coordination polymers 1 and 2 were characterized by X-ray single crystal diffraction and elemental analysis.The structural analysis showed that 1 and 2 were both one-dimensional chain structures.

关 键 词：镉 配合物 合成 晶体结构 

分 类 号：O614.24*2[理学—无机化学]