五元环氟化物的合成及应用  

Synthesis and application of five-membered ring fluoride

作　　者：张呈平 庆飞要 贾晓卿 权恒道 ZHANG Chengping;QING Feiyao;JIA Xiaoqing;QUAN Hengdao(School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China)

机构地区：[1]北京理工大学化学与化工学院,北京100081

出　　处：《化工学报》2020年第9期3963-3978,共16页CIESC Journal

基　　金：国家环境保护部环境保护对外合作中心的清洗行业消耗臭氧层物质替代技术研发和推广项目(C/Ⅲ/T/14/072).

摘　　要：综述了以双环戊二烯(DCPD)、六氯环戊二烯(HCCPD)或八氯环戊烯(OCP)为起始原料合成1,2-二氯六氟环戊烯(F6-12)、1,3-二氯六氟环戊烯(F6-13)、1-氯七氟环戊烯(F7-1)、1,1,2,2,3,3,4-七氟环戊烷(F7A)、1,1,2,2,3,3-六氟环戊烷(F6A)、顺式-1,1,2,2,3,3,4,5-八氟环戊烷(cis-F8A)、八氟环戊烯(F8E)、3,3,4,4,5,5-六氟环戊烯(F6E)、1,3,3,4,4,5,5-七氟环戊烯(F7E)等系列五元环氟化物的合成路线,以及五元环氟化物在电子清洗、电子刻蚀、合成电子氟化液的应用。提出了五元环氟化物的合成研究重点是新型合成路线的开发、高催化活性且对人体健康无害的过程催化剂的开发,以及无污染化工艺过程的开发,而应用研究重点是开发五元环氟化物的电子级产品以及开发五元环氟化物的下游产品。The synthetic routes for a series of five-membered ring fluorides by using dicyclopentadiene(DCPD),hexachlorocyclopentadiene(HCCPD)or octachlorocyclopentene(OCP)as starting materials are reviewed,including 1,2-dichlorohexafluorocyclopentene(F6-12),1,3-dichlorohexafluorocyclopentene(F6-13),1-chloroheptafluorocyclopentene(F7-1),1,1,2,2,3,3,4-heptafluorocyclopentane(F7A),1,1,2,2,3,3-hexafluorocyclopentane(F6A),cis-1,1,2,2,3,3,4,5-octafluorocyclopentane(cis-F8A),octafluorocyclopentene(F8E),3,3,4,4,5,5-hexafluorocyclopentene(F6E),1,3,3,4,4,5,5-heptafluorocyclopentene(F7E)and the application of five-membered ring fluorides in electronic cleaning,electronic etching,and synthesis of electronic fluoride solutions.It is proposed that the synthesis research of five-membered ring fluorides mainly focus on the development of novel synthetic routes,catalysts with high activity and no harm to human health,and green manufacturing.Furthermore,the application research focus on the development of the electronic grade products and the downstream products of fivemembered ring fluorides.

关 键 词：五元环氟化物 1 1 2 2 3 3 4-七氟环戊烷 电子清洗 电子刻蚀 电子氟化液 催化 催化剂 催化剂活化 

分 类 号：TQ203.2[化学工程—有机化工] TQ213