Photoinduced palladium-catalyzed carbonylation of halides with weak nucleophiles  

利用光诱导与钯催化实现卤代物与弱亲核试剂的羰基化反应

作　　者：Xuan Jiang Yue Jia Wen-Jing Xiao Liang-Qiu Lu 姜烜;贾玥;肖文精;陆良秋(CCNU-uOrrawa Joint Research Centre,Key Laboratory of Pesticides&Chemical Biology,Ministry o f Education,College of Chemistry,Central China Normal University,Wuhan 430079,China;State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China)

机构地区：[1]CCNU-uOrrawa Joint Research Centre,Key Laboratory of Pesticides&Chemical Biology,Ministry o f Education,College of Chemistry,Central China Normal University,Wuhan 430079,China [2]State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China

出　　处：《Science Bulletin》2020年第20期1696-1698,共3页科学通报（英文版）

摘　　要：Carbon monoxide,as a C1 synthon,plays a fundamentally important role in modern chemical synthesis.Despite great achievements,the development of sustainable and effective CO conversion methods is still in high demand[1,2].Transitionmetal-catalyzed carbonylation of halides has been established as a powerful platform for assembling valuable carbonyl compounds,including(thio)esters,amides,aldehydes and ketones[3].

关 键 词：羰基化反应 亲核试剂 卤代物 

分 类 号：O621.251[理学—有机化学]