N-杂环卡宾配体在聚合反应中的研究进展  

Research Advances of N-Heterocyclic Carbene Ligands in Polymerization

作　　者：孔勇[1] Kong Yong(Research Institute of Petroleum Engineering,Sinopec,Beijing,100101)

机构地区：[1]中国石化石油工程技术研究院,北京100101

出　　处：《化学通报》2020年第9期792-798,共7页Chemistry

基　　金：国家科技重大专项(2016ZX05021004-002);中石化科技部项目(PE19001、P18001-2、P17002-8)资助。

摘　　要：N-杂环卡宾(NHC)配体的优异催化性能引起了人们的广泛关注,已成功应用于多种烯烃聚合反应。本文主要介绍NHC及其在开环易位聚合、烯烃配位聚合和原子转移自由基聚合等反应中的应用。在此基础上,指出了今后NHC配体在聚合反应研究的发展方向。N-heterocyclic carbene ligands have attracted extensive attention due to their excellent catalytic performance,and have been widely utilized in a variety of olefin polymerization reactions.According to the recent reports,N-heterocyclic carbene were briefly introduced,firstly.The recent research advances of the application in ring-opening metathesis polymerization,olefin coordination polymerization,atom transfer radical polymerization,and other polymerization were focused on.The development trends of N-heterocyclic carbene ligands in polymerization were also prospected.

关 键 词：N-杂环卡宾 金属配合物催化剂 聚合反应 

分 类 号：O631.5[理学—高分子化学] O641.4[理学—化学] O643.36