诱导聚集与协同配位策略构筑金属氧合团簇及其有机骨架  

Induced aggregation and synergistic coordination strategy in metal oxo clusters and their organic frameworks

作　　者：方伟慧 杨国昱[1] Wei-Hui Fang;Guo-Yu Yang(MOE Key Laboratory of Cluster Science,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 102488,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China)

机构地区：[1]北京理工大学化学与化工学院,原子分子簇科学教育部重点实验室,北京102488 [2]中国科学院福建物质结构研究所,结构化学国家重点实验室,福州350002

出　　处：《中国科学：化学》2020年第9期975-985,共11页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21771181,21831001,21571016,91122028,20725101);中国科学院青年创新促进会(编号:2017345)资助项目。

摘　　要：随着金属有机骨架(metal organic frameworks,MOFs)和金属氧合团簇(metal oxo clusters,MOCs)两大领域的不断发展壮大,形成了一种新的材料—金属簇有机骨架(metal cluster organic frameworks,MCOFs).由于这种材料同时结合了金属氧合团簇的特性和孔隙特性,使化学家们产生了浓厚的研究兴趣.本文综述了稀土氧合团簇有机骨架(lanthanide cluster organic frameworks,LnCOFs)的主要进展,提出了诱导聚集成簇和协同配位策略.通过文献调研分析,阐明该策略不仅适合MCOFs,也适用于新颖MOCs的构筑.The new class of materials of metal cluster organic framework(MCOFs)derive from metal organic framework(MOFs)and metal oxo clusters(MOCs).In recent years,MCOFs has attracted considerable attention for their combination of metal oxo clusters and porous characteristics.We herein summarize the progress of lanthanide cluster organic framework(LnCOFs),and point out the induced aggregation and synergetic coordination strategy.This strategy is suitable for making MCOFs and MOCs.

关 键 词：氧合团簇 金属簇有机骨架 诱导聚集 协同配位 

分 类 号：O641.4[理学—物理化学]