有机聚合物负载铑催化剂在氢甲酰化反应中的应用研究进展  

Progress in Application of Organic Polymers Supported Rhodium Catalysts in Hydroformylation

作　　者：宗玲博 陈建宾 任新意 张国营 贾肖飞 Zong Lingbo;Chen Jianbin;Ren Xinyi;Zhang Guoying;Jia Xiaofei(Shandong Key Laboratory of Biochemical Analysis,College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao,Shandong 266042;Shandong Provincial Key Laboratory of Molecular Engineering,School of Chemistry and Chemical Engineering,Qilu University of Technology,Jinan 250353;Shanghai Key Laboratory of Green Chemistry and Chemical Process,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai 200241)

机构地区：[1]青岛科技大学化学与分子工程学院,山东省生化分析重点实验室,山东青岛266042 [2]齐鲁工业大学化学与制药工程学院,山东省分子工程重点实验室,济南250353 [3]华东师范大学化学与分子工程学院绿色化学与化工过程绿色化上海市重点实验室,上海200241

出　　处：《有机化学》2020年第8期2308-2321,共14页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.21703116,51702180);青岛科技大学化学学部开放基金(Nos.QUSTHX201932,QUSTHX202010)资助项目。

摘　　要：氢甲酰化反应是工业上最重要的均相反应之一.该反应被广泛应用于醛的生产,生产的醛还可以进一步转为具有高附加值的醇、酸等衍生物.与均相反应相比,多相催化在催化剂循环、产物和催化剂分离等方面具有优势.近年来,有机聚合物负载铑催化剂在非均相的甲酰化反应中表现出优秀的催化活性、高的选择性和好的循环性等优点,因而受到广泛关注.总结了有机聚合物负载催化剂在氢甲酰化反应中应用研究进展,主要介绍了催化剂的合成、材料特点和应用,最后对发展前景进行了展望.Hydroformylation is considered one of the most important homogenously catalyzed processes in dustry.Hydroformylation has been widely used in the production of aldehydes,and aldehydes can also be further converted into high value-added alcohols,acids and other derivatives.Compared with the homogeneous reaction,the heterogeneous catalysts present significant advantages in terms of recyclability,separation of catalysts and products and so on.In recent years,organic polymer-supported rhodium catalysts have shown excellent catalytic activity,high selectivity,and good recycleability in heterogeneous hydroformylation,and have attracted widespread attention.The research progress of the application of organic polymer supported catalysts in hydroformylation is summarized,including synthesis,material characteristics and application of supported catalysts.Finally,the prospect of the reaction is discussed.

关 键 词：铑 氢甲酰化 有机聚合物 非均相催化剂 

分 类 号：O621.251[理学—有机化学]