N-磺酰-1,2,3-三唑的合成方法及其在有机合成中的应用研究进展  

Progress in Synthesis of N-Sulfonyl-1,2,3-triazole and Its Application in Organic Synthesis

作　　者：张文生 许文静[2] 张斐 马春玉[1] 马科友[1] 李焱[2] Zhang Wensheng;Xu Wenjing;Zhang Fei;Ma Chunyu;Ma Keyou;Li Yan(Department of Metallurgy and Chemical Engineering,Jiyuan Vocational and Technical College,Jiyuan,Henan 459000;Institute of Synthetic Technology,Jiaozuo Teachers College,Jiaozuo,Henan 454100;Jiaozuo Vocational and Technological School,Jiaozuo,Henan 454100)

机构地区：[1]济源职业技术学院冶金化工系,河南济源459000 [2]焦作师范高等专科学校合成技术研究所,河南焦作454100 [3]焦作职业技术学校,河南焦作454100

出　　处：《有机化学》2020年第8期2338-2352,共15页Chinese Journal of Organic Chemistry

基　　金：基金资助:河南省教育厅自然科学重点研究计划(No.20B150014);济源职业技术学院2020年重点科研课题(No.JZXY-2020-58)资助项目。

摘　　要：N-磺酰-1,2,3-三唑是一类重要的五元含氮有机化合物,被广泛应用于合成各类含氮有机化合物,尤其是杂环或氨基取代芳环化合物.介绍了N-磺酰-1,2,3-三唑的主要合成方法,对其作为重氮亚胺和Rh-卡宾亚胺中间体的前体,通过开环构建各类有机化合物在2018~2019年期间的最新研究进展进行了综述.N-Sulfonyl-1,2,3-triazole,an important class of five-membered nitrogen-containing organic compounds,has been found processing widespread application in the synthesis of various nitrogen-containing organic compounds,especially heterocyclic or amino-substituted aromatic rings.The synthetic methods of N-sulfonyl-1,2,3-triazole are introduced.Besides,the progress on constructions of various organic compounds via ring-opening reaction of N-sulfonyl-1,2,3-triazoles as precursor of α-diazoimine and Rh-carbene imine intermediates in the past two years is reviewed.

关 键 词：N-磺酰-1 2 3-三唑 α-重氮亚胺 Rh-卡宾亚胺 

分 类 号：O623.7[理学—有机化学]