纯碳链与过渡金属的螯合化学  

Chemistry of carbon chain ligands chelating transition metals

作　　者：郑雪娟 张弘[1] 夏海平 ZHENG Xuejuan;ZHANG Hong;XIA Haiping(State Key Laboratory of Physical Chemistry of Solid Surfaces,Collaborative Innovation Center of Chemistry for Energy Materials,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China)

机构地区：[1]厦门大学化学化工学院,固体表面物理化学国家重点实验室,能源材料化学协同创新中心,福建厦门361005

出　　处：《厦门大学学报（自然科学版）》2020年第5期864-878,共15页Journal of Xiamen University：Natural Science

基　　金：中央高校基本科研业务费专项(20720190042)。

摘　　要：碳-金属键的形成与断裂是金属有机化学的核心问题,也是金属参与各种有机化学反应的关键步骤.然而,传统的金属有机化合物多数不稳定且合成条件苛刻,制约了碳-金属键构建的相关研究.近10多年来,夏海平团队始终致力于在一个金属中心上构筑尽可能多的碳-金属σ键,发现了一系列全新的芳香性金属杂环结构基元,逐步建立了“碳龙化学”.本文主要对一系列含2~5个碳-金属σ键的金属杂环化合物进行综述.The formation and breaking-up of carbon-metal bonds is the most important issue in organometallic chemistry,which has also been regarded as a key step in various reactions involving metal and metal catalysis.However,most of organometallic compounds are unstable and difficult to synthesize in mild conditions,which greatly restrict their further studies.Over the past ten years,we have devoted to construct as many as possible carbon-metalσbonds in one metal center,which has resulted in a series of novel metallaaromatics frameworks,and gradually establish"Carbolong Chemistry".This review summarized a series of metallacycles containing two to five carbon-metalσbonds.

关 键 词：金属杂环化合物 碳龙化学 多齿配体 碳-金属σ键 

分 类 号：O621.25[理学—有机化学]