非茂金属络合物催化烯烃聚合研究进展  

Research Progress of Non-Metallocene Complexes for Olefin Polymerization

作　　者：郭建双 王原 王新威 Guo Jianshuang;Wang Yuan;Wang Xinwei(Shanghai Research Institute of Chemical Industry Co.,Ltd.,Shanghai 200062,China;State Key Laboratory of Polyolefins and Catalysis,Shanghai 200062,China;Shanghai Key Laboratory of Catalysis Technology for Polyolefins,Shanghai 200062,China)

机构地区：[1]上海化工研究院有限公司,上海200062 [2]聚烯烃催化技术与高性能材料国家重点实验室,上海200062 [3]上海市聚烯烃催化技术重点实验室,上海200062

出　　处：《上海塑料》2020年第3期1-11,共11页Shanghai Plastics

基　　金：上海市青年科技启明星计划(20QB1403600)。

摘　　要：非茂金属络合物是近些年发展起来的高性能烯烃聚合催化剂,由非茂化合物作为配体与金属前体配位络合生成,以其极高的活性、聚合物分子结构的可控性、多重活性聚合等特性受到关注。综述了非茂金属络合物的研究进展,按照配体骨架和金属中心分类,阐述了非茂金属络合物催化烯烃聚合特性,为其深入研究及工业化应用提供参考。Non-metallocene complexes are the high-performance catalysts for the polymerization of olefins which have been developed in recent years.They are formed by the coordination of non-metallocene ligands and metals.They have attracted much attention due to their extremely high activity,controllability of polymer molecular structure,and multiple living polymerization characteristics.The research progress of non-metallocene complexes is reviewed,and the catalytic properties of non-metallocene complexes for olefin polymerization are described according to the classification of ligand skeleton and metal center,which provides a reference for the further research and industrial applications.

关 键 词：非茂金属络合物 催化剂 烯烃 聚合 

分 类 号：TQ325.1[化学工程—合成树脂塑料工业]