Synthesis,Crystal Structure and Catalytic Activity Palladium(Ⅱ)Complexes Containing Bulky Azole Ligands  

作　　者：ZHANG Meng-Yao ZHANG Ying-Ying ZHANG Hui-Xin WANG Shen WANG Ya-Qi ZENG Yong-Fei LIU Gui-Yan 张梦姚;张颖颖;张慧欣;王珅;王亚琦;曾永飞;刘桂艳(Tianjin Key Laboratory of Structure and Performance for Functional Molecules,Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry(Tianjin Normal University),Ministry of Education,College of Chemistry,Tianjin Normal University,Tianjin 300387,China)

机构地区：[1]Tianjin Key Laboratory of Structure and Performance for Functional Molecules,Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry(Tianjin Normal University),Ministry of Education,College of Chemistry,Tianjin Normal University,Tianjin 300387,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第9期1669-1674,1556,共7页结构化学（英文）

基　　金：Supported by the Natural Science Foundation of Tianjin(No.16JCYBJC19700);the National Natural Science Foundation of China(No.21771138)。

摘　　要：Bulky azole ligands in combination with PdCl2 provide three new palladium(II)complexes.All these complexes,as pre-catalysts,have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings(0.1 mol%)under mild conditions in air.

关 键 词：palladium(II)complexes crystal structure catalytic activity Suzuki-Miyaura cross-coupling sterically hindered aryl chlorides 

分 类 号：O641.4[理学—物理化学] O643.36[理学—化学]