Syntheses, Crystal Structures, and Electrochemical Properties of Dehydroabietic Acid-based Schiff Bases  

作　　者：CAI Xu-Min CHEN Xin-Fei MU Tian-Qi LIN Yu-Ting HUANG Shen-Lin YAO Min-Xia 蔡旭敏;陈新菲;穆天齐;蔺玉婷;黄申林;姚敏霞(College of Chemical Engineering,Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass,Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals,Nanjing Forestry University,Nanjing 210037,China;School of Chemistry and Molecular Engineering,Nanjing Tech University,Nanjing 211816,China)

机构地区：[1]College of Chemical Engineering,Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass,Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals,Nanjing Forestry University,Nanjing 210037,China [2]School of Chemistry and Molecular Engineering,Nanjing Tech University,Nanjing 211816,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第9期1699-1706,1557,共9页结构化学（英文）

基　　金：Supported by the National Natural Science Foundation of China(21601087 and 21401101);the Topnotch Academic Programs Project(TAPP);the Priority Academic Program Development of Jiangsu Higher Education Institution(PAPD)。

摘　　要：Two Schiff bases(DAMBA-Fc and DAA-Fc)derived from dehydroabietic acid have been successfully synthesized and characterized by means of FT-IR,elemental analysis,HRMS,and NMR spectroscopy.The crystal structure of DAA-Fc can be determined by single-crystal X-ray diffraction.The compound is of monoclinic system,space group P21 with a=10.7379(6),b=7.5004(4),c=33.3294(18)?,β=97.996(3)o,Z=4,V=2658.2(3)?3,Mr=481.48,Dc=1.203 g/cm3,S=1.034,μ=0.585 mm-1,F(000)=1032,the final R=0.0566 and wR=0.0701 for 5645 observed reflections(I>2σ(I)).In addition,cyclic and differential pulse voltammogram techniques have been applied to differentiate the redox properties of the aromatic-and aliphatic-connected Schiff bases DAMBA-Fc and DAA-Fc,respectively.

关 键 词：dehydroabietic acid FERROCENE Schiff base crystal structure electrochemical properties 

分 类 号：O621.3[理学—有机化学]