A review on metal-organic frameworks for photoelectrocatalytic applications  

作　　者：Feihu Mu Benlin Dai Wei Zhao Lili Zhang Jiming Xu Xujing Guo 

机构地区：[1]Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials,Jiangsu Engineering Laboratory for Environment Functional Materials,Jiangsu Collaborative Innovation Center of Regional Modem Agriculture and Environmental Protection,School of Chemistry and Chemical Engineering,Huaiyin Normal University,Huaian 223300,China [2]College of Resources and Environment,Chengdu University of Information Technology,Chengdu 610225,China

出　　处：《Chinese Chemical Letters》2020年第7期1773-1781,共9页中国化学快报（英文版）

基　　金：the Natural Science Foundation of Jiangsu Province of China(Nos.BK20160430,BK20181070);the National Natural Science Foundation of China(No.51808250);the Project Funded by China Postdoctoral Science Foundation(Nos.2016M591757,2017M610336);the jiangsu Planned Projects for Postdoctoral Research Funds of China(No.1601179C)。

摘　　要：Semiconductor-based photoelectrocatalytic processes have attracted considerable research interest for solar energy collection and storage.Photoelectrocatalysis is a heterogeneous photocatalytic process in which a bias potential is applied to a photoelectrode,and thus the photoelectrocatalytic performance is closely related to the photoelectrode prepared by semiconductors.Among various semiconductors,metal-organic frameworks(MOFs)have attracted more and more attention because of their unique properties such as optical properties and adjustable structure.Herein,a comprehensive review on different MOFs(Ti-based,Zn-based,Co-based,Fe-based,Cu-based,and mixed metal-based MOFs)for heterogeneous photoelectrocatalysis is carried out and,in particular,the application of this technique for CO2 conversion and water splitting is discussed.In addition,the challenges and development prospects of MOFs in photoelectrocatalysis are also presented.

关 键 词：MOFS PHOTOELECTROCATALYSIS PHOTOELECTRODE CO2 conversion Water splitting 

分 类 号：O643.3[理学—物理化学]