N5衍生物近期研究进展  

Recent Research Progress of N5 Derivatives

作　　者：陆明[1] 许元刚 王鹏程[1] 林秋汉[1] LU Ming;XU Yuan-gang;WANG Peng-cheng;LIN Qiu-han(School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China)

机构地区：[1]南京理工大学化工学院,江苏南京210094

出　　处：《火炸药学报》2020年第5期457-464,476,I0001,共10页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金(No.21771108,No.21975127);江苏省研究生科研与实践创新计划项目(KYCX19_0308)。

摘　　要：从实验和理论方面综述了N5(包括“V”型N^+5和环状N-5)衍生物的近期研究进展。介绍了N^+5及其衍生物N^+5AsF-6、N^+5SbF-6和N^+5[P(N3)6]-等10个离子盐的合成以及N^+5M-(M=Sb(OH)6、Sb(OH)4F2、AlF6、AlF4、BF4、B(CF3)4、PF6、AsF6和SbF6)和N^+5B(N3)-4的理论研究;N-5及其衍生物[Na(N5)(H2O)]·2H2O等19个金属配合物(其中12个配位聚合物)和(N5)6(H3O)3(NH4)4Cl等17个非金属含能离子盐的合成以及BaN5、CuN5和M(N5)3(M=Al、Ga、Sc和Y)的理论研究,对N-5衍生物的能量性能进行了比较;并简单介绍了N-5的高压合成方法;指出了N5衍生物的发展趋势。附参考文献45篇。The recent research progress of N5(including“V”type N^+5 and cyclic N-5)derivatives is reviewed in terms of experiment and theory.The syntheses of N^+5 and its 10 ion salts,such as N^+5AsF-6,N^+5SbF-6 and N^+5[P(N3)6]-;the theoretical studies of N^+5M-(M=Sb(OH)6,Sb(OH)4F2,AlF6,AlF4,BF4,B(CF3)4,PF6,AsF6 and SbF6)and N^+5B(N3)4-;the syntheses of N-5 and its derivative[Na(N5)(H2O)]·2H2O etc.19 metal complexes(of which 12 coordination polymers)and(N5)6(H3O)3(NH4)4Cl etc.17 non-metallic energetic ion salts;and the theoretical studies of BaN5,CuN5 and M(N5)3(M=Al,Ga,Sc and Y)are introduced,and the energetic performances of N-5 derivatives are compared.The development process of high-pressure synthesis of N-5 is summarized,and the development trends of N-5derivatives are pointed out with 45 references.

关 键 词：全氮材料 N^+5 N-5 全氮衍生物 高能量密度材料 能量性能 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O62[理学—有机化学]