响应曲面分析优化镧钐配合物/PAM的制备及性能研究  

Preparation and property of La/Sm/PAM complex optimized by response surface analysis

作　　者：高春焕 李运涛[1] 郝瑾 Gao Chunhuan;Li Yuntao;Hao Jin(School of Chemistry and Chemical Engineering,Shaanxi University of Science and Technology,Xi’an710021)

机构地区：[1]陕西科技大学化学与化工学院,西安710021

出　　处：《化工新型材料》2020年第9期133-136,共4页New Chemical Materials

基　　金：国家自然科学基金(21475081)。

摘　　要：为更好地提高稀土配合物的发光性能,采用非共价方法制备了一种新型的高发光性能材料。发现苯甲酸(BA)和1,10-邻菲咯啉水合物(Phen)与Sm3+和La3+配位形成异核稀土络合物。通过傅立叶变换红外光谱、X射线电子光谱、荧光光谱、有机元素分析仪和紫外光谱等手段对制备的产物进行表征。结果表明:复合材料具有较强的发光强度、较长的使用寿命和较好的热稳定性。此外,La3+离子对材料有很强的敏化作用,对提高材料的发光强度有显著作用。然后利用单因素实验和响应曲面相结合的方法对实验进行优化。Goal:a novel material with high luminescent performance was prepared using a noncovalent approach.Process and method:herein,a heteronuclear rare earth complex was revealed in which the benzoic acid(BA)and 1,10-phenanthroline hydrate(Phen)coordinated with Sm3+andLa3+.The as-prepared products were characterized via fourier-transform infrared spectroscopy,X-ray electron spectroscopy,fluorescence spectrometer,organic elemental analyzer,ultraviolet spectrometer and thermogravimetric analysis.Result and conclusion:the hybrid materials exhibited strong luminescence intensity,long lifetime and good thermal stability.Besides,La3+ions had a strong sensitizing effect on materials and played a significant role in improving the luminescence intensity.Then the experiment was optimized by combining the single-factor experiment with the response surface.

关 键 词：稀土配合物 发光性能 溶剂热法 制备 响应曲面优化法 

分 类 号：O614.33[理学—无机化学]