金属-有机骨架衍生催化剂在二氧化碳加氢和费托合成反应中的应用  

Recent Advances in Application of Metal-Orgainic Framework-Derived Catalysts for Hydrogenation of Carbon Dioxideand Fischer-Tropsch Synthesis

作　　者：刘军辉[1] 宋亚坤 宋春山[2,3] 郭新闻[3] LIU Junhui;SONG Yakun;SONG Chunshan;GUO Xinwen(College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang,Henan 471023,China;Department of Energy and Mineral Engineering,EMS Energy Institute,PSU-DUT Joint Center for Energy Research,Pennsylvania State University,Pennsylvania State,16802,USA;State Key Laboratory of Fine Chemicals,PSU-DUT Joint Center for Energy Research,School of Chemical Engineering,Dalian University of Technology,Dalian,Liaoning 116024,China)

机构地区：[1]河南科技大学化工与制药学院,河南洛阳471023 [2]宾夕法尼亚州立大学能源研究所,美国宾夕法尼亚州16802 [3]大连理工大学化工学院,宾州-大连联合能源研究中心,精细化工国家重点实验室,辽宁大连116024

出　　处：《应用化学》2020年第10期1099-1111,共13页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(21908043);河南省重点攻关项目(192102310209)资助。

摘　　要：CO 2加氢和费托合成反应是C1化学中重要的研究领域,CO 2加氢制备高附加值化学品和燃料有助于降低大气中CO 2浓度,减轻化石燃料消耗的压力;费托合成反应是以非石油资源为原料生产液体燃料和化学品的重要路径。开发新型、高效、稳定的催化剂是CO 2加氢和费托合成反应的关键点之一。利用金属-有机骨架(Metal-Organic Frameworks,MOFs)材料的特点制备的MOFs衍生催化剂在CO 2加氢和费托合成反应中具有较好的应用前景。本文综述了CO 2加氢和费托合成反应中MOFs衍生催化剂的制备方法,以及催化剂在各反应中的催化性能,并对目前所存在的问题以及今后的发展进行了总结和展望。Hydrogenation of CO 2 and Fischer-Tropsch synthesis reactions are the important research fields in C1 chemistry.Hydrogenation of CO 2 to form value-added chemicals and fuels is beneficial for reducing the CO 2 concentration in the atmosphere and mitigating the pressure on fossil fuel consumption.Fischer-Tropsch synthesis is considered as a significant route to produce liquid fuels and chemicals from non-petroleum sources.Development of novel,efficient,and stable catalysts is an urgent point for hydrogenation of CO 2 and Fischer-Tropsch synthesis.The metal-organic framework(MOF)-derived catalysts have a good application prospect in hydrogenation of CO 2 and Fischer-Tropsch synthesis.This paper reviews the preparation methods of MOF-derived catalysts and the catalytic performance in the reactions.In addition,the current problems are summarized and the future development of this field is pointed out.

关 键 词：二氧化碳加氢 费托合成 金属-有机骨架热解 催化剂 

分 类 号：O643.3[理学—物理化学]