Anderson型杂多酸作为催化剂在有机合成中的应用  

Application of Anderson Type Heteropoly Acids as Catalysts in Organic Synthesis

作　　者：魏哲宇 常亚林 余焓 韩生 魏永革[2] Wei Zheyu;Chang Yalina;Yu Han;Han Sheng;Wei Yongge(College of Chemistry and Environmental Engineering,Shanghai Institute of Technology,Shanghai 201418;Department of Chemistry,Tsinghua University,Beijing 100084)

机构地区：[1]上海应用技术大学化学与环境工程学院,上海201418 [2]清华大学化学系,北京100084

出　　处：《化学学报》2020年第8期725-732,共8页Acta Chimica Sinica

基　　金：国家自然科学基金(Nos.21971134,21631007,21225103)资助。

摘　　要：Anderson型杂多酸(通式为[XM6O24]n-)是一类具有特殊结构和性质的多金属-氧簇无机化合物,由于其分子结构易于化学修饰和可设计性以及其在材料、催化和医药等领域具有很高的应用价值,因此一直受到研究者们的广泛关注.近几年来,Anderson型杂多酸在催化有机氧化反应中的应用对于绿色催化过程的研究逐渐显露出非常重要的意义.本综述对Anderson型杂多酸在有机合成反应中的催化应用进行了相关的调研,根据Anderson型多金属氧酸盐的结构分类对这些工作进行了归纳概述与总结.这将为Anderson型杂多酸的催化应用以及为绿色催化的研究提供新的思路.Anderson type heteropoly acids,also known as Anderson type polyoxometalates,are a kind of important structures in polyoxometalates.Their general structural formula can be expressed as[XM6 O24]n-,in which the core heteroatom X can almost be replaced by almost any metal or nonmetal element in the periodic table.Due to unique structure easy to be modified with organic ligands and designability,as well as their potential applications in materials,catalysis and medicines,Anderson type heteropoly acids have been widely concerned by researchers.In recent years,the application of Anderson type heteropoly acids in organic synthesis has gradually shown great significance for the study of green catalytic process.In this paper,the catalytic application of Anderson type heteropoly acids in organic synthesis has been reviewed and summarized according to the structure classification of Anderson type polyoxometalates.This will be helpful for the researchers to further study the catalytic application of Anderson heteropoly acids and provides new ideas for the research of green catalysis.

关 键 词：杂多酸 ANDERSON结构 有机合成 分子催化 绿色化学 

分 类 号：O643.36[理学—物理化学] O641.4[理学—化学]