形状记忆聚合物变形模式研究进展  

Research Progress of Shape Memory Polymer Deformation Mode

作　　者：张澜[1] 马愫倩[1] 王寒冰[2] 梁云虹[1] 张志辉[1] Zhang Lan;Ma Suqian;Wang Hanbing;Liang Yunhong;Zhang Zhihui(The Key Laboratory of Bionic Engineering,Ministry of Education,Jilin University,Changchun 130025,China;Jilin Province Product Quality Supervision and Inspection Institute,Changchun 130000,China)

机构地区：[1]吉林大学教育部仿生工程重点实验室,长春130025 [2]吉林省产品质量监督检验院,长春130000

出　　处：《化学学报》2020年第9期865-876,共12页Acta Chimica Sinica

基　　金：国家重点研发计划(2018YFB1105100,2018YFA0703300和2018YFC2001300);国家自然科学基金(51822504,51675223和91848204);吉林省科技攻关项目(20180201051GX);吉林大学科技创新研究团队计划(2017TD-04);装备预研教育部联合基金(2018G944J00084);中国博士后科学基金(2019M661204)资助。

摘　　要：近年来,形状记忆聚合物(SMP)的发展取得了明显进步,其自身的优势也得到了充分的展示.形状记忆聚合物是一种刺激响应智能材料,在特定的外部刺激条件下可以根据预先设计的方式改变形状.形状记忆聚合物具有密度低、变形量大、驱动方式丰富、生物相容性好等一系列优势,使其在航空航天、生物医学、仿生工程、电子元件、智能机器人等领域有着巨大的应用潜力.为了更好地适应不同应用和不同领域的需求,形状记忆聚合物的变形模式也在不断地创新,本综述介绍了形状记忆聚合物不同的变形方式及其相关应用的进展,并对形状记忆聚合物面临的挑战和其潜在的研究方向进行了展望.Shape memory polymers are the most widely studied smart deformable materials at present. Due to their low density, large deformation, high stress resistance, various driving methods, good biocompatibility, easier modification and processing, shape memory polymers have become a cutting-edge research in the field of smart materials. Under certain external stimulus(such as temperature, light, electric field, magnetic field, pH, specific ions, enzymes, etc.), shape memory polymers can change their shapes according to pre-designed way and quickly change from temporary shape to permanent shape. Shape memory polymers have shown great application potential in aerospace, biomedicine, bionic engineering, electronic devices, intelligent robots and other fields, which effectively overcome the bottleneck problems in the corresponding fields. In order to make the shape memory polymers more suitable for various fields, not only a simple deformation process from a temporary shape to a permanent shape is needed, the deformation mode should also be improved to adapt the actual situation in practical applications. In this paper, the deformation modes of shape memory polymers are divided into four categories, including the simple dual shape memory deformation mode, the multiple shape memory deformation mode with multiple temporary shapes, the self-folding deformation mode, and the reversible two-way shape memory deformation mode. Multiple shape memory polymers generally have multiple reversible switches or a wide range of temperature switches, which have greater freedom in practical applications. The self-folding structure can spontaneously fold/unfold to the desired shape under stimulation conditions without artificially giving shape, so it has great application prospects in the fields of space systems and self-assembly systems. The reversible shape memory polymer can reversibly convert between permanent and temporary shapes under stimulation conditions, which show great application prospects in the fields of sensors and drivers. T

关 键 词：形状记忆聚合物 智能材料 变形模式 刺激响应 

分 类 号：TQ317[化学工程—高聚物工业]