A Novel Route to Synthesize N,N-Dimethyl Arylmethylamines from Aryl Aldehydes, Hexamethylenetetramine and Hydrogen  

作　　者：Zhengang Ke Bo Yu Yunyan Wu Yanfei Zhao Peng Yang Shien Guo Zhimin Liu 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,Key Laboratory of Colloid,Interface and Thermodynamics,CAS Research/Education Centre for Excellence in Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China [2]University of Chinese Academy of Sciences,Beijing 100049,China [3]Physical Science Laboratory,Huairou National Comprehensive Science Center,Beijing 101407,China

出　　处：《Chinese Journal of Chemistry》2020年第8期842-846,共5页中国化学（英文版）

基　　金：This work was financially supported by the Beijing Municipal Science&Technology Commission(No.Z191100007219009);Chinese Academy of Sciences(Grant No.QYZDY-SSW-SLH013).

摘　　要：Developing simple and green routes to access valuable chemicals is of significance.Herein,we present a green and novel route to synthesize N,N-dimethyl arylmethylamines(DAMAs)from hexamethylenetetramine(HMTA)and aryl aldehydes in the presence of hydrogen,and a series of DAMAs can be obtained in good yields.This approach opens the precedent for HMTA as N,N-dimethylamine source to synthesize chemicals with N,N-dimethylamine group,which has promising applications for N-containing chemicals synthesis.

关 键 词：synthesis. AMINES SYNTHESIZE 

分 类 号：O62[理学—有机化学]