大豆的热分解特性及其动力学探究  

Study on thermal decomposition characteristics and kinetics of soybean

作　　者：周一帆 姚丛雪 王靖文 郭文文 宋磊[1] 牧小卫 胡源[1] ZHOU Yifan;YAO Congxue;WANG Jingwen;GUO Wenwen;SONG Lei;MU Xiaowei;HU Yuan(State Key Laboratory of Fire Science,China University of Science and Technology,Hefei 230027,Anhui,China)

机构地区：[1]中国科学技术大学火灾科学国家重点实验室,安徽合肥230027

出　　处：《化工学报》2020年第S02期187-194,共8页CIESC Journal

基　　金：国家重点研发计划项目(2017YFC0805901)。

摘　　要：动态热重分析(TGA)被用来研究大豆的热降解动力学,通过改变大豆热解时的升温速率(5,10,20和40℃/min)以及气氛条件(氮气和空气)探索了大豆在不同热解条件下的热解特性。并结合对相应热解条件下的动力学参数(表观活化能Ek)进行求解,探究了大豆的火灾安全性。结果表明,大豆的热解可以分为四个阶段:前两个阶段对应自由水和结晶水的脱除,后两个阶段对应主要成分(淀粉、蛋白质和脂肪)的次分解阶段和主要分解阶段。后两个阶段,由于氧气的存在,导致大豆的热分解出现了不同的历程,800℃时的残炭率降低。且与氮气气氛下热解相比,大豆在空气气氛下表现出更低的反应活化能和火灾安全性。In this paper,the thermal degradation kinetics of soybean was studied by dynamic thermogravimetry(TGA).The thermal decomposition characteristics and kinetics of soybean under different pyrolysis conditions were explored by changing the heating rate(5,10,20 and 40℃/min)and the atmosphere conditions(nitrogen and air).According to the trend of TGA and DTG curves,the pyrolysis of soybean can be divided into four stages:the first two stages correspond to the removal of free water and crystal water,and the last two stages correspond to the secondary decomposition stage and the main decomposition stage of main components(starch,protein and fat).In the latter two stages,due to the presence of oxygen,the thermal decomposition process of soybean appeared different,and the activation energy and carbon residue rate of the reaction decreased.Compared with pyrolysis in nitrogen atmosphere,soybean showed lower activation energy and fire safety in air atmosphere.In this paper,the difference of pyrolysis kinetics of soybean in different atmosphere was studied for the first time,and the intrinsic law of pyrolysis and its fire safety were revealed.

关 键 词：热解 生物质 热力学 活化能 热重分析 

分 类 号：O5551[理学—热学与物质分子运动论] O5552[理学—物理]