掺杂ZnO的Ru-Fe/ZrO2催化苯选择加氢制环己烯的性能研究  

STUDY ON THE CATALYTIC PERFORMANCE OF ZnO-DOPED Ru-Fe/ZrO2 FOR SELECTIVE HYDROGENATION OF BENZENE TO CYCLOHEXENE

作　　者：黄振旭 孙海杰 秦会安 王玲 贾潘潘 李颖欣 张文慧 Huang Zhenxu;Sun Haijie;Qin Huian;Wang Ling;Jia Panpan;Li Yingxin;Zhang Wenhui(College of Chemistry and Chemical Engineering, Zhengzhou Normal University, Zhengzhou 450044, He’nan, China)

机构地区：[1]郑州师范学院化学化工学院,河南郑州450044

出　　处：《精细石油化工》2020年第6期34-38,共5页Speciality Petrochemicals

基　　金：河南省科技攻关重点项目(162102210333);河南省高等学校重点科研项目(19B150021);郑州地方高校大学生创新训练计划项目(ZDC2019002)。

摘　　要：采用浸渍-沉淀法制备了掺杂ZnO的Ru-Fe/ZrO2催化剂,并通过XRD和TEM等手段对其进行了表征。结果表明,催化剂中引入了ZnO,Ru和ZnO在载体上高度分散,使催化剂的比表面积和平均孔径都有较大增加。催化剂Zn和Zr之间的协同效应可以同时提高苯的转化率和环己烯的选择性。使用掺杂ZnO比例为1∶10的催化剂进行苯加氢反应,反应时间20 min,环己烯最高产率为51.77%。The ZnO-doped Ru-Fe/ZrO2 catalyst was prepared by the impregnation-precipitation method and characterized by means of XRD and TEM.The results showed that ruthenium and zinc oxide were highly dispersed on the carrier,and the adding of zinc oxide promoted that catalysts had higher texture property.The synergistic effect between Zn and Zr could increase the conversion of benzene and the selectivity of cyclohexene at the same time.A cyclohexene yield of 51.77%is achieved on the ZnO-doped Ru-Fe/ZrO2 catalyst at 20 min when the prepared catalyst has a ratio of ZnO to ZrO2 of 1∶10.

关 键 词：掺杂氧化锌 苯选择加氢 环己烯 

分 类 号：O643.32[理学—物理化学]