Controllable Skeleton Rearrangement of 3-Substituted Cyclobutanones under Basic Conditions  

作　　者：Peng Yan Qiang Zhou Jun Chen Ping Lu 

机构地区：[1]Research Center for Molecular Recognition and Synthesi,Department of Chemistry,Fudan University,220 Handan Lu,Shanghai 200433,China

出　　处：《Chinese Journal of Chemistry》2020年第10期1103-1106,共4页中国化学（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(Nos.21772024,21921003);1000-Youth Talents Program and Fudan University(for the start-up grant)。

摘　　要：Summary of main observation and conclusion Divergent skeleton rearrangements of cyclobutanones under simply basic conditions have been de-scribed.The reaction pathway is controlled by the nature of 2 group on 3-substituted cyclobutanones,leading to the formation of various lactones,lac-tams and acids.Preliminary results on enantioselective reaction were also reported.

关 键 词：SUBSTITUTED SKELETON simply 

分 类 号：O62[理学—有机化学]