Controllable Skeleton Rearrangement of 3-Substituted Cyclobutanones under Basic Conditions  被引量:1

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作  者:Peng Yan Qiang Zhou Jun Chen Ping Lu 

机构地区:[1]Research Center for Molecular Recognition and Synthesi,Department of Chemistry,Fudan University,220 Handan Lu,Shanghai 200433,China

出  处:《Chinese Journal of Chemistry》2020年第10期1103-1106,共4页中国化学(英文版)

基  金:This work was supported by the National Natural Science Foundation of China(Nos.21772024,21921003);1000-Youth Talents Program and Fudan University(for the start-up grant)。

摘  要:Summary of main observation and conclusion Divergent skeleton rearrangements of cyclobutanones under simply basic conditions have been de-scribed.The reaction pathway is controlled by the nature of 2 group on 3-substituted cyclobutanones,leading to the formation of various lactones,lac-tams and acids.Preliminary results on enantioselective reaction were also reported.

关 键 词:SUBSTITUTED SKELETON simply 

分 类 号:O62[理学—有机化学]

 

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