N-Heterocyclic Carbene Organocatalysis: Activation Modes and Typical Reactive Intermediates  

作　　者：Xingkuan Chen Hongling Wang Zhichao Jin Yonggui Robin Chi 

机构地区：[1]Department of Chemistry,Jinan University,Guangzhou,Guangdong 510632,China [2]Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering,Key Laboratory of Green Pesticide and Agricultural Bioengineering,Minisry of Education,Guizhou University,Huaxi District,Guiyang,Guizhou 550025,China [3]Division of Chemistry&Biological Chemistr,School of Physical&Mathematical Sciences,Nanyang Technological University,Singopore 637371,Singapore

出　　处：《Chinese Journal of Chemistry》2020年第10期1167-1202,共36页中国化学（英文版）

基　　金：We acknowledge finantlal suppart by the Natlorial Nalural Science Foundation of China(No.21772029);the National Key Technologies R&D Program(No.2014BAD23B01);The 10 Talent Plan(Shicengci)of Guizhou Province([2016]5649);the Natural Science Foundation of Guizhou Province([2018]2802);the Gui-zhou Province First-Class Disciplines Project(GNYL(2017)008);Jinan University(Guangzhou),Guizhou University of Traditional Chinese Medicine(China)and Guizhou University(China)。

摘　　要：N-Heterocyclic carbene(NHC)organocatalysis has been developed as an important approach in modern organic synthesis.Versatile activation modes within NHC organocatalysis have been established with countless transformations being realized in both efficient and selective fashion.We would like to provide an overview on the key progresses achieved within this field in the past two decades.Since numerous excellent reviews have been documented within this area,we will mainly focus on the scientific development of this research field based on the basic reaction modes and typical reaction intermediates.

关 键 词：synthesis. CATALYSIS HETEROCYCLIC 

分 类 号：O62[理学—有机化学]