基于卟啉及其衍生物的硫化氢检测进展  

Recent Advances of Porphyrin and Its Derivatives in Hydrogen Sulfide Detection

作　　者：陈露 张璇 尹耀新 魏峥嵘 黎厚斌[1] CHEN Lu;ZHANG Xuan;YIN Yaoxin;WEI Zhengrong;LI Houbin(School of Printing and Packaging,Wuhan University,Wuhan 430079,China;Gansu Yinguang Chemical Industry Group,Baiyin Gansu 730000,China)

机构地区：[1]武汉大学印刷与包装系,湖北武汉430079 [2]甘肃银光化学工业集团,甘肃白银730000

出　　处：《包装学报》2020年第5期1-10,共10页Packaging Journal

摘　　要：硫化氢既是有毒物质又是生物体内重要气体信号分子,所以对硫化氢检测的研究十分重要。卟啉及其衍生物作为传感器材料,具有良好的化学稳定性和光学稳定性,与硫化氢结合后会产生光电变化,是检测硫化氢的优良材料。简述了硫化氢的检测手段、卟啉的性质以及卟啉与硫化氢的反应原理,并按照不同的传感器类别综述了卟啉在硫化氢检测中的应用,同时还对卟啉在硫化氢检测的应用领域进行了展望。Hydrogen sulfide(H2S)is toxic and an important gas signal molecule in the organism as well,so it is important to study the detection of H2S.As sensor materials,porphyrins and their derivatives have good chemical and optical stability and photoelectric changes will be produced when combined with H2S.Therefore,porphyrins and their derivatives are excellent materials for detecting H2S.The detection methods of H2S,the properties of porphyrin and the reaction principle of porphyrin and H2S are introduced.The applications of porphyrins in H2S detection are reviewed in terms of different sensor categories,while the application field of porphyrins in H2S detection is prospected.

关 键 词：硫化氢 卟啉 传感器 荧光探针 

分 类 号：O659[理学—分析化学]