稀土-钛氧簇合物的研究进展  

Recent Advances in Lanthanide-titanium-oxo Clusters

作　　者：李观俊 龙腊生[1] 孔祥建[1] 郑兰荪[1] LI Guanjun;LONG Lasheng;KONG Xiangjian;ZHENG Lansun(Collaborative Innovation Center of Chemistry for Energy Materials,State Key Laboratory of Physical Chemistry of Solid Surface,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China)

机构地区：[1]厦门大学化学化工学院化学系,固体表面物理化学国家重点实验室,能源材料化学协同创新中心,厦门361005

出　　处：《高等学校化学学报》2020年第12期2577-2586,共10页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:21871224,21673184,21721001)资助.

摘　　要：稀土-钛氧簇合物作为团簇化学的一个新分支,不但结合了稀土和钛离子的特性,而且由于二者的协同效应而表现出优异的光、电、磁和催化性能.本文综合评述了不同配体稀土-钛氧簇合物的合成与结构,介绍了稀土-钛氧簇合物的代表性成果,并对其合成策略和发展前景进行了总结和展望.As a new branch of cluster chemistry,lanthanide-titanium-oxo clusters not only integrate the characteristics of lanthanide and titanium ions,but also often show a synergistic effect of the two elements,so they usually have excellent optical,electoral,magnetic and catalytic properties.The lanthanide-titanium-oxo cluters attract more attention because its accurate structure model is more conducive to understand the relation⁃ship between structure and activity.In this paper,the synthesis and structures of lanthanide-titanium-oxo clusters are outlined based on different ligands and the representative properties are introduced.The synthetic strategies and development prospects of lanthanide-titanium-oxo clusters are prospected.It is hoped that this review can provide insight into future research on lanthanide-titanium-oxo clusters.

关 键 词：稀土-钛氧簇合物 合成 结构 荧光 光催化 

分 类 号：O614[理学—无机化学] O641[理学—化学]