“可控自组装体系及其功能化”重大研究计划取得系列重要研究成果  

Review of Major Research Plan on“Controlled Self-assembly Systems and Functionalization”

作　　者：高飞雪[1] 陈拥军[1] 刘冬生[2] 刘鸣华[3] 田中群[4] 张希[2] Feixue Gao;Yongjun Chen;Dongsheng Liu;Minghua Liu;Zhongqun Tian;Xi Zhang(Department of Chemical Sciences,National Natural Science Foundation of China,Beijing 100085,P.R.China;Department of Chemistry,Tsinghua University,Beijing 100084,P.R.China;Institute of Chemistry Chinese Academy of Sciences,Beijing 100190,P.R.China;College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian Province,P.R.China)

机构地区：[1]国家自然科学基金委员会,化学科学部,北京100085 [2]清华大学化学系,北京100084 [3]中国科学院化学研究所,北京100190 [4]厦门大学化学化工学院,福建厦门100190

出　　处：《物理化学学报》2020年第11期158-164,共7页Acta Physico-Chimica Sinica

摘　　要：2005年美国科学(Science)杂志在纪念该刊创办125周年之际,把"我们能推动化学自组装走多远?"列为未来最具挑战性的25个科学问题之一,受到世界各国科学家的广泛关注和重视。"十一五"期间,国家自然科学基金委员会组织多领域的科学家充分讨论和酝酿从而提出了"可控自组装体系及其功能化"重大研究计划。计划实施以来,我国科学家开拓和认识了多种新型弱相互作用力,发展了多种具有"中国标签"的新组装基元,建立了类似于有机"人名反应"的组装新方法,实现了多组分、多层次组装体的功能,构建了一批有重要科学意义和潜在实用价值的可控自组装体系,实现了从跟随到原创的跨越式发展,全面推动了我国化学可控自组装研究走向国际舞台的中心。本文介绍了"可控自组装体系及其功能化"重大研究计划的总体科学目标、总体布局和实施思路,以及该重大研究计划资助下取得的系列重要研究成果。In 2005,the Science magazine,in commemorating the 125th anniversary of its founding,proposed 25 most challenging scientific issues in the future.One of the issues,“How far can we push chemical self-assembly?”has attracted the attention of scientists all over the world.During the 11th Five Year Plan period,NSFC convened scientists from various fields and proposed a major research project,“Controllable self-assembly system and its functionalization”.Since the implementation of this project,Chinese scientists have developed and recognized a variety of noncovalent interactions,constructed numerous assembly building blocks with the“Chinese label”,established a new assembly method similar to an organic“name reaction”,realized the functions of multi-component and multi-level assemblies,and constructed a batch of controllable self-assembly systems having scientific importance and potential practical value.They have achieved great leap forward from following to original innovation,and brought the research of chemical self-assembly in China to move forward to the center of international stage.In this study,we examined the overall scientific goals,general layout of the plan,and ideas for implementation of the major research program“Controllable Self-Assembly System and its Functionalization”,as well as an array of significant research accomplishments made possible through the funding received by the program.

关 键 词：可控自组装 组装驱动力 组装基元 组装方法与理论 功能材料 

分 类 号：O641.3[理学—物理化学]