高碳烯烃多相羰基合成催化剂研究进展  

Research Progress in Catalysts for the High Olefins Heterogeneous Carbonylation

作　　者：石博文 朱楠 杨自玲 孙向前 SHI Bo-wen;ZHU Nan;YANG Zi-ling;SUN Xiang-qian(Institute of Coal Chemical Industry Technology CHN Energy Ningxia Coal Industry Co.,LTD.,Yinchuan 750411,Ningxia,China)

机构地区：[1]国家能源集团宁夏煤业有限责任公司煤炭工业技术研究院,宁夏银川750411

出　　处：《合成材料老化与应用》2020年第6期139-141,145,共4页Synthetic Materials Aging and Application

基　　金：宁夏回族自治区重点研发计划一般科技项目(2018BDE63001)。

摘　　要：针对均相羰基合成工业化应用中催化剂分离困难与催化活性组分流失问题,综述了固载羰基合成催化剂与液/液两相催化体系的研究进展。对固载催化体系、水/有机两相工艺、温控相转移催化工艺、有机/离子液体两相工艺、scCO2体系、有机氟两相催化工艺等多相羰基合成催化剂进行了详细论述,分析了各种工艺的优缺点以及应用前景。In view of the difficulty of catalyst separation and loss of active components in the industrial application of carbonyl synthesis,the research progress of solid supported carbonyl synthesis catalyst and liquid/liquid biphase catalyst system was reviewed.The solid supported catalyst system,water/organic biphase process,temperature controlled phase transfer catalyst process,organic/ionic liquid biphase process,scCO2 system,organic fluorine biphase catalyst and so on were discussed in detail.The advantages,disadvantages and application prospects of various processes weae discussed and evaluated.

关 键 词：高碳醇 羰基合成 固载羰基合成催化剂 液/液两相催化体系 煤制油 

分 类 号：TQ223.12[化学工程—有机化工]