锰-ttmb骨架材料荧光和热重性质  

Luminescence and Thermal Stability Properties of Manganese-ttmb Frameworks

作　　者：王海鹏 刘利锋[2] 李宝龙[3] WANG Hai-Peng;LIU Li-feng;LI Bao-long(School of Chemistry and Environmental Engineering,Shanxi Datong University,Shanxi Datong,037009;School of Physics and Electronics Science,Shanxi Datong University,Shanxi Datong 037009;Key Laboratory of Organic Synthesis of Jiangsu Province,Soochow University,Suzhou Jiangsu,215123)

机构地区：[1]山西大同大学化学与化工学院,山西大同037009 [2]山西大同大学物理与电子科学学院,山西大同037009 [3]苏州大学江苏省有机合成重点实验室,江苏苏州215123

出　　处：《山西大同大学学报（自然科学版）》2020年第6期7-10,共4页Journal of Shanxi Datong University(Natural Science Edition)

基　　金：国家自然科学基金资助项目[21171126]。

摘　　要：选用多齿柔性配体1,3,5-三(三氮唑-1-甲基)-2,4,6-三甲基苯(ttmb)及第二配体5-磺基间苯二甲酸(HSO3bdc)与锰盐自组装合成了金属有机骨架材料{[Mn(ttmb)2(HSO3bdc)(H2O)3]}n,对其结构、荧光和热重性质进行表征,结果表明该骨架材料呈现一维链状结构,具有良好的荧光性能。In this paper,metal-organic frameworks{[Mn(ttmb)2(HSO3bdc)(H2O)3]}n was synthesized by self-assembly reaction of 1,3,5-tri(1,2,4-triazol-1-ylmethyl)-2,4,6-Trimethylbenzene(ttmb)as the first flexible ligand and 5-sulfonic acid(HSO3bdc)as the second ligand with manganese salt.The structure,fluorescence and thermogravimetric properties were characterized,and the results showed that the framework presented a one-dimensional chain structure with good fluorescence performance.

关 键 词：金属有机骨架材料 荧光性能 1 3 5-三(三氮唑-1-甲基)-2 4 6-三甲基苯 

分 类 号：O614.7[理学—无机化学]