TDI Char制备液体燃料方法  

A novel method of preparing liquid fuel from TDI Char

作　　者：焦澄远 郑樑 余根鼎 吴诗佳 李静玲 JIAO Chengyuan;ZHENG Liang;YU Gending;WU Shijia;LI Jingling(School of Ecological Environment and Urban Construction, Fujian University of Technology, Fuzhou 350118, China;Center of Safe and Energy-saving Engineering Technology for Urban Water Supply and Drainage System, Fujian University of Technology, Fuzhou 350118, China;Fujian Huasha Institute of Energy and Design CO., Ltd., Fuzhou 350003, China;Institute of Chemical Safety, Fujian University of Technology, Fuzhou 350118, China)

机构地区：[1]福建工程学院生态环境与城市建设学院,福建福州350118 [2]福建工程学院城镇给排水系统安全与节能工程技术中心,福建福州350118 [3]福建省华厦能源设计研究院有限公司,福建福州350003 [4]福建工程学院化工安全研究所,福建福州350118

出　　处：《福建工程学院学报》2020年第6期549-552,563,共5页Journal of Fujian University of Technology

基　　金：福建省教育厅自然科技项目(JAT190427);福州市科技基金项目(2019-G-51);福建工程学院科研启动项目(GY-Z160042)。

摘　　要：提出以甲醇超临界流体用于TDI Char制备消解液体燃料的技术。研究了制备技术条件并进行表征。结果表明,反应温度270℃,反应时间120 min条件下,TDI Char的消解率达95%。氧弹量热仪实验揭示,所得单位液体燃料的燃烧热值较直接燃烧TDI Char增加了2.3倍。The technique of applying methanol supercritical fluid into the preparation and degradation of liquid fuel with TDI Char was proposed.The experimental preparation conditions were studied and characterized.Results demonstrate that the degradation efficiency of TDI Char reached 95%at approximately 270℃and with a reaction time of 120 min.The calorimeter experiments revealed that the heat of combustion per unit liquid fuel was significantly increased by 2.3 twice as much as that of direct combustion by TDI Char itself.

关 键 词：甲苯二异氰酸酯 焦油残渣 甲醇 超临界流体 液体燃料 绿色化学 

分 类 号：TQ511[化学工程]