Pb3(CO3)2(OH)2 Is an Active Phase in Electrocatalytic CO2 Reduction to Formate  被引量:1

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作  者:TAO Zixu WANG Hailiang 

机构地区:[1]Department of Chemistry,Yale University,New Haven,CT 06511,USA

出  处:《Chemical Research in Chinese Universities》2020年第6期1145-1146,共2页高等学校化学研究(英文版)

摘  要:Determining the catalytically active phase in electrochemical CO2 reduction has been challenging.In their work recently published in Nature Communications on July 8,2020,Zhang et al.studied the phase transition of a tannin-lead(Ⅱ)complex in electrochemical CO2 reduction and revealed that the in-situ formed hydrocerussite[Pb(CO3)2(OH)]is the stable active phase for formate production.This new finding may help settle the debate on the real active site of Pb-based materials for CO2 electroreduction.

关 键 词:(Ⅱ) PHASE finding 

分 类 号:O62[理学—有机化学]

 

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