P5W30基配合物的结构与性能研究进展  

Structures and properties of P5W30-based complexes:a review

作　　者：刘国成[1] 赵静 李晨曦 钟宝琦 李爽[1] LIU Guocheng;ZHAO Jing;LI Chenxi;ZHONG Baoqi;LI Shuang(College of Chemistry and Chemical Engineering,Bohai University,Jinzhou 121013,China)

机构地区：[1]渤海大学化学化工学院,辽宁锦州121013

出　　处：《渤海大学学报（自然科学版）》2020年第2期105-111,共7页Journal of Bohai University:Natural Science Edition

基　　金：国家自然科学基金项目(No:21401010)。

摘　　要：将多金属氧酸盐阴离子作为无机配体引入金属-有机配合物的合成研究在近几年已得到快速的发展.作为一类新颖的多酸阴离子(Preyssler型,简称P5W30),由P5W30构筑的金属-有机配合物因其具有特殊的结构和良好的光、电、磁等物理化学性质,已成为一种新型功能性杂化材料.迄今为止,大量的P5W30基配合物已被合成并用于多个领域.本文综述了P5W30可溶性盐的制备、P5W30的结构、P5W30基配合物的结构以及其在电催化、染料吸附、磁性等方面的性能研究,为后续构建性能优异的新型配合物材料提供参考.In recent years,the synthesis of metal-organic complexes by introducing polyoxometalates as inorganic ligands has been developed rapidly.As a kind of novel polyoxoanion(Preyssler type,abbreviating P5W30),the metal-organic complexes constructed by P5W30 have become a new functional hybrid material due to their special structure and good physicochemical properties such as light,electricity,magnetism and so on.So far,a large number of P5W30-based complexes have been synthesized and used in many fields.In this paper,the preparation of soluble salt of P5W30,the structure of P5W30,the structure of P5W30-based complexes and its performance researches in electrocatalysis,dye adsorption,magnetism and other aspects were reviewed,providing reference for the subsequent construction of new complex materials with excellent performance.

关 键 词：多金属氧酸盐 晶体结构 配合物 性能 

分 类 号：O614.61[理学—无机化学]