共价有机骨架材料在电化学储能中的应用研究进展  

Research progress of covalent organic frameworks in electrochemical energy storage

作　　者：纪群 董宣 李雪[1] 宋鹏豪 路乃群[3] 王存国[1] JI Qun;DONG Xuan;LI Xue;SONG Penghao;LU Naiqun;WANG Cunguo(Key Laboratory of Rubber-plastics,Ministry of Education,Shandong Province Key Lab of Rubber-plastics,Qingdao University of Science and Technology,Qingdao 266042,China;Key Laboratory of Nanodevices and Applications&Collaborative Innovation Center of Suzhou Nano Science and Technology,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(CAS),Suzhou 215123,China;College of Automation and Electronic Engineering,Qingdao University of Science and Technology,Qingdao 266110,China)

机构地区：[1]青岛科技大学橡塑材料与工程教育部重点实验室山东省橡塑材料与工程重点实验室,山东青岛266042 [2]中科院苏州纳米技术与纳米仿生研究所纳米器件及相关材料研究部,江苏苏州215123 [3]青岛科技大学自动化与电子工程学院,山东青岛266110

出　　处：《化工科技》2020年第6期58-65,共8页Science & Technology in Chemical Industry

基　　金：国家高端外国专家项目(中组部办公厅字2017-21);山东省教育厅项目(SDYJG19089);山东省潍坊市高层次创新创业人才计划项目(潍办字2013-69)。

摘　　要：共价有机骨架材料(Covalent Organic Frameworks,COFs)是一种新型多孔结晶高分子材料,由于其热稳定性高、孔隙丰富、比表面积大、分子结构可调和活性位点多等特性,被认为是一种非常有发展前途的储能材料。作者对COFs材料的主要合成方法和最新合成策略进行了介绍,综述了二维COFs材料在锂离子电池、钠离子电池、锂/硫电池中的应用研究进展状况。最后,对二维COFs材料在电化学储能中的应用进行了展望。Covalent organic frameworks(COFs),as a burgeoning porous crystalline polymer material with many characteristics,such as high thermal stability,abundant pores,large specific surface area,adjustable molecular structure,and lots of active sites,is considered to be a very promising energy storage material.The main synthesis methods and latest synthesis strategies of COFs materials are introduced in this paper,and the progress of the application research of two-dimensional COFs materials in lithium ion batteries,sodium ion batteries,and lithium sulfur batteries are summarized.Finally,the application of 2D COFs materials in electrochemical energy storage was prospected.

关 键 词：共价有机骨架材料 二维多孔聚合物 锂离子电池 钠离子电池 锂/硫电池 

分 类 号：O646[理学—物理化学] O621[理学—化学]