Synthesis of T-Extended Carbazoles via One-Pot C-c Coupling and Chlorination Promoted by FeCl3  

作　　者：Yang Qian Jia Shang Zhen-Hua Lyu Xin Huang Ai-jiao Guan Li-Jin Xu Han-Yuan Gong 

机构地区：[1]Department of Chemistry,Renmin University of China,Zhongguancundajie 59,Beijing 100872,China [2]College of Chemistry,Beijing Normal University,Xinjiekouwaidajie 19,Beijing 100875,China [3]Institute of Chemistry,Chinese Academy of Sciences,Zhongguancunbeiyijie 2,Beijing 100190,China

出　　处：《Chinese Journal of Chemistry》2020年第12期1538-1544,共7页中国化学（英文版）

基　　金：H.-Y.G.is grateful to the National Natural Science Foundationof China(21971022,21672025,and 21472014);National BasicResearch Program of China(973 Program 2015CB856502);the Young One Thousand-Talents scheme,the Fundamental Research Funds for the Central Universities,the Beijing Municipal Commission of Education,the Beijing National Laboratory for Molecular Science(BNLMS),and Beijing Normal University for financial support.

摘　　要：of main observation and conclusion A facile synthesis,functionalization,and emission property of N-doped carbon-rich halogenated compound 3,6,12,15-tetrachloro-9-phenyl-9H-tetrabenzo[a,c,g#i]carbazole(ClCbz)was reported.Cost-effective FeCI3 catalyst serves to break eight C—H bonds of 1,2,3,4,5-pentaphenylpyrrole(1)and subsequently construct two C—C and four C—Cl bonds in one pot with a high yield of up to 75%.

关 键 词：BONDS CONCLUSION facile 

分 类 号：O62[理学—有机化学]