Design and Application of Indole-Based Allylic Donors for Pd-Catalyzed Decarboxylative Allylation Reactions  

作　　者：Qing-Qing Hang Si-Jia Liu Lei Yu Ting-Ting Sun Yu-Chen Zhang Guang-Jian Mei Feng Shi 

机构地区：[1]School of Chemistry and Materials Science,Jiangsu Normal University,Xuzhou,Jiangsu 221116,China

出　　处：《Chinese Journal of Chemistry》2020年第12期1612-1618,共7页中国化学（英文版）

基　　金：We are grateful for financial support from NSFC(Nos.21772069,21831007 and 21702077);the Natural Science Founda-tion of Jiangsu Province(No.BK20170227);Six Kinds of Talents Project of Jiangsu Province(No.SWYY-025).

摘　　要：of main observation and conclusion A new class of indole-based allylic donors have been designed and developed for palladium-catalyzed decarboxylative allylations.In addition,the first application of these indole-based allylic donors in palladium-catalyzed decarboxylative[3+2]cydoaddition and allylic amination has been achieved by reacting with isocyanates and sulfonyl amines,respectively.This approach represents the first design of indole-based allylic donors,which is helpful for settling the challenge of designing and developing new class of heterocycle-based allylic donors for Pd-catalyzed decarboxylative allylation reactions.Moreover,the application of this new class of allylic donors in cycloadditions and substitutions will add new contents to the research field of decarboxylative allylation.

关 键 词：palladium catalyzed ALLYL 

分 类 号：O62[理学—有机化学]