Low Valent Palladium Clusters: Synthesis, Structures and Catalytic Applications  

作　　者：Qian Liu Liang Zhao 

机构地区：[1]Kkey laboratory of Bioorganic Phosphorus Chemistry&Chemical Biology,Department of Chemistry,Tsinghua University,Beijing 100084,China

出　　处：《Chinese Journal of Chemistry》2020年第12期1897-1908,共12页中国化学（英文版）

基　　金：National Natural Science Foundation of China (Nos.21772111,21821001,91956125 and 21661132006);the Top-Notch YoungTalents Program of China are gratefully acknowledged.

摘　　要：Ay one of the most common transition metal catalysts,mononuclear palladium catalysts have been develped systematcally and a widely recognizedcatalytic mechanism featured with a pd/Pd catalytic cycle for a palladium center has been proposed.However,recent research works have revealed thatpalladium clusters may also be catalysts or catalyti intermediates involved in the catalytic processes.This major discovery brings new perspectives for adeep and comprehensive understanding of the PRd-catalyzed reaction mechanisms.Combining with the latest advances in the field of organometllicchemistry,we here highlight the synthesis,structures,and catalytic reactivities of palladium custer compounds.This reviw discusses severalwel-defined syntheticstrategies and diversepalladum cluster-based catalytic systems in detail,to provide insights into the rational design of promisingpalladium cluster catalysts and the effective search for appropriate synthetic methods.

关 键 词：PALLADIUM CATALYTIC CLUSTER 

分 类 号：O64[理学—物理化学]