用工业固体废料合成沸石分子筛的研究进展  

Recent Progresses on the Synthesis of Zeolites from the Industrial Solid Wastes

作　　者：王彬宇 李莉[1] 李菁[2] 靳科研 张少卿 张佳楠[3] 闫文付[1] WANG Binyu;LI Li;LI Jing;JIN Keyan;ZHANG Shaoqing;ZHANG Jianan;YAN Wenfu(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China;Research Institute of Jilin Petrochemical Company,PetroChina,Jilin 132001,China;School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001,China)

机构地区：[1]吉林大学无机合成与制备化学国家重点实验室,化学学院,长春130012 [2]中国石油天然气股份有限公司吉林石化分公司研究院,吉林132001 [3]郑州大学材料科学与工程学院,郑州450001

出　　处：《高等学校化学学报》2021年第1期40-59,共20页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:U1967215,21835002,21621001);高等学校学科创新引智计划项目(批准号:B17020)资助.

摘　　要：系统总结了以工业固体废料为原料合成沸石分子筛材料的最新研究进展,讨论了以粉煤灰、珍珠岩工业废料、煤矸石、流体催化裂化(FCC)废催化剂、锂矿渣、铝土矿渣、废瓷料和废弃玻璃等工业固体废料为原料,合成LTA,FAU,MFI,CHA,GIS,SOD,ANA和KFI沸石分子筛材料的工艺方法,及其在污水中重金属离子的脱除、空气中CO2的捕获、氮氧化物的选择性还原等实际应用中的性能,并对未来工业固体废料合成沸石分子筛的发展趋势进行了展望.Thisreview summarizes the latest progresses on the synthesis of zeolites using industrial solid wastes as raw materials.The industrial solid wastes include fly ash,perlite waste,coal gangue,spent FCC catalyst,lithium slag,bauxite residue,waste porcelain and glass.The zeolites crystallized from these industrial sold wastes are LTA,FAU,MFI,CHA,GIS,SOD,ANA and KFI.The key in the pretreatment of each solid waste was presented.Finally,the trend and challenges in the synthesis of zeolites using the industrial solid wasteswere discussed.

关 键 词：沸石 分子筛 工业固体废料 粉煤灰 铝土矿渣 

分 类 号：O611.4[理学—无机化学]