柱芳烃与离子液体络合体系的研究进展  

Research progress of pillararene and ionic liquid complexation systems

作　　者：郭立颖[1] 马恩庆 刘坤 白晓琳[1] 王海玥[1] GUO Li-ying;MA En-qing;LIU Kun;BAI Xiao-lin;WANG Hai-yue(School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, China;Heavy Oil Catalysis Workshop, No. 2 Petroleum Plant of Fushun Petrochemical Company of PetroChina, Fushun 113004, China)

机构地区：[1]沈阳工业大学石油化工学院,辽宁辽阳111003 [2]中国石油抚顺石化分公司石油二厂重油催化车间,辽宁抚顺113004

出　　处：《沈阳工业大学学报》2021年第1期35-41,共7页Journal of Shenyang University of Technology

基　　金：国家自然科学基金项目(21706163).

摘　　要：柱芳烃具有独特的富电子空腔和易于功能化的特性,在材料科学、生命科学、环境科学等领域呈现出良好的应用前景.将离子液体与柱芳烃结合可以在离子液体的可设计性结构、无饱和蒸气压、可重复使用等特点的基础上进一步提高其应用性能.介绍了温敏型、pH值型、光敏型柱芳烃与离子液体主客体络合体系的研究成果,总结了近几年柱芳烃与离子液体络合体系的发展趋势,并对络合体系在催化领域的应用前景进行了展望.Pillararenes have unique characteristics of electron-rich cavity and easy functionalization and show a good application prospect in materials science,life science,environmental science and other fields.Their combination with ionic liquids can further improve the application performances of ionic liquids,based on their designable structure,unsaturated vapor pressure and reusability characteristics.Research results of temperature sensitive,pH sensitive and photosensitive host-guest complexation systems of pillararenes and ionic liquids were reviewed,the development trend of pillararene and ionic liquid complexation systems in recent years was summarized,and the application prospect of complexation systems in the catalysis field was outlooked.

关 键 词：柱芳烃 离子液体 主客体络合 超分子 催化剂 温敏型 pH值型 光敏型 

分 类 号：TQ241.4[化学工程—有机化工]