Sulfonylcalix[4]arene-based Coordination Supercontainers  

作　　者：HE Can SHENG Tian-Pu DAI Feng-Rong CHEN Zhong-Ning 何灿;盛天谱;戴枫荣;陈忠宁(College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China)

机构地区：[1]College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第12期2077-2084,2053,共9页结构化学（英文）

基　　金：supported by the National Natural Science Foundation of China(21673239 and 21501179)。

摘　　要：Sulfonylcalix[4]arenes-based coordination containers,namely metal-organic supercontainers(MOSCs),are a new class of coordination containers constructed from the self-assembly of divalent metal ions,suitable carboxylate linkers,and sulfonylcalix[4]arenes container precursor.MOSCs feature both endo cavity surrounded by carboxylate linkers and exo cavities originated from the upper rim of sulfonylcalix[4]arenes.The molecular topologies and endo cavity of MOSCs are tuneable via judicious design of carboxylate linkers,while the modulation of endo cavity are accessible by chemical modification on the para substituent group of the sulfonylcalix[4]arenes.In this paper,recent advances and typical examples of design and functionalization of MOSCs are presented.

关 键 词：coordination container arene metal-organic supercontainer SELF-ASSEMBLY 

分 类 号：O641.4[理学—物理化学]