新型大环芳烃的研究进展  

Recent Advances in Novel Macrocyclic Arenes

作　　者：李晶[1,2] 韩莹 陈传峰[1,2] Li Jing;Han Ying;Chen Chuanfeng(CAS Key Laboratory of Molecular Recognition and Function,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190;University of Chinese Academy of Sciences,Beijing 100049)

机构地区：[1]中国科学院化学研究所分子识别与功能院重点实验室,北京100190 [2]中国科学院大学,北京100049

出　　处：《有机化学》2020年第11期3714-3737,M0008,共25页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.91856117,21332008)资助项目.

摘　　要：杯芳烃、柱芳烃及其类似物均由羟基或烷氧基取代的芳环通过亚甲基或次甲基桥连而形成的大环分子,统称为大环芳烃.大环芳烃由于具有结构特殊、易于合成与衍生化、富电子空腔等特点以及其在超分子化学等领域中的广泛应用,因而一直引起人们极大的关注与兴趣,成为了最重要和研究最多的合成大环主体分子之一.近年来,随着大环与超分子化学的快速发展,除杯芳烃、柱芳烃等经典大环芳烃之外,各种不同类型的具有新颖结构的大环芳烃分子不断地被合成报道,新型大环芳烃设计构建及其功能研究也成为了大环与超分子化学中一个新的重点与热点研究课题.综述了新型大环芳烃的研究进展,重点介绍过去十余年尤其是近几年发展的新型大环芳烃分子合成及其性能.希望该综述能够有助于大环芳烃相关的研究工作,并促进大环芳烃化学的发展.Calixarenes,pillararenes and their analogues are composed of hydroxy-or alkoxy-substituted aromatic rings bridged by methylene or methenyl groups,which can be collectively called as macrocyclic arenes.Macrocyclic arenes have attracted much attention and increasing interests because of their unique structures,easily synthesis and derivatization,electron-rich cavities and wide applications in supramolecular chemistry,and they have also become one of the most significant and studied synthetic macrocyclic hosts during the last decades.Recently,with the rapid development of macrocycles and supramolecular chemistry,various types of novel macrocyclic arenes except the classic macrocyclic arenes such as calixarenes and pillararenes have been reported.The construction and functionalization of novel macrocyclic arenes have become the new focus and hot topic of macrocyclic and supramolecular chemistry.The recent advances in the synthesis and properties of novel macrocyclic arenes are summarized.It is expected that this review will be helpful to the research of macrocyclic arenes and promote the development of macrocyclic arene chemistry.

关 键 词：大环芳烃 合成 主客体化学 自组装 超分子化学 

分 类 号：O625.1[理学—有机化学]