三(三甲硅基)硅烷/氧气促进和可见光加速烷基碘向醇的转化  

Tris(trimethylsilyl)silane/O2-Promoted and Photo-accelerated Conversion of Alkyl Iodides to Alcohols

作　　者：李健羽 曾金龙 陈剑锋 赵宝国 Li Jianyu;Zeng Jinlong;Chen Jianfeng;Zhao Baoguo(Key Laboratory of Resource Chemistry of Ministry of Education and Shanghai Key Laboratory of Rare Earth Functional Materials,College of Chemistry and Materials Science,Shanghai Normal University,Shanghai 200234)

机构地区：[1]上海师范大学化学与材料科学学院资源化学教育部重点实验室和上海市稀土功能材料重点实验室,上海200234

出　　处：《有机化学》2020年第11期3853-3857,M0011,共6页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21672148);上海市教育委员会(No.2019-01-07-00-02-E00029);上海市绿色能源化工工程研究中心资助项目.

摘　　要：发展了一种由烷基碘向醇转化的温和方法.该反应的发生需要三(三甲硅基)硅烷/氧气存在,同时可以通过可见光照射加速.不同类型的烷基碘化物,如一级、二级和三级烷基碘化物都能顺利发生反应,以38%〜99%的收率得到相应的醇化合物.A mild method for the conversion of alkyl iodides to alcohols was developed.The transformation was promoted by tris(trimethylsilyl)silane/O2 and accelerated by photoredox catalysis under visible light irradiation conditions.Various alkyl iodides,including primary,secondary and tertiary iodides,can be smoothly converted to the corresponding alcohols in 38%~99%yields.

关 键 词：三(三甲硅基)硅烷 光催化 碳自由基 烷基碘 醇 

分 类 号：O623.41[理学—有机化学]