一/二价离子分离膜材料研究进展  

Recent progress of membrane materials for mono-/di-valent ions separation

作　　者：黄清波 刘公平 金万勤 HUANG Qingbo;LIU Gongping;JIN Wanqin(State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemical Engineering,Nanjing Tech University,Nanjing 211816,Jiangsu,China)

机构地区：[1]南京工业大学化工学院,材料化学工程国家重点实验室,江苏南京211816

出　　处：《化工学报》2021年第1期334-350,共17页CIESC Journal

基　　金：国家自然科学基金项目(21922805,21776125)。

摘　　要：一/二价离子分离膜在能源存储和转换、污染监测和控制、清洁工业过程等领域发挥重要作用。本文旨在回顾近年来一/二价离子分离膜材料的研究进展,重点综述聚合物膜、混合基质膜及金属有机骨架和二维材料等新型膜用于一/二价离子分离的研究现状,深入讨论界面聚合、层层组装、沉积、共混等不同制备方法对膜微结构和分离性能的影响,探讨一/二价离子分离膜面临的主要挑战和未来研究方向。Mono-/di-valent ion separation membranes play an important role in energy storage and conversion,pollution monitoring and control,and clean industrial processes.This article aims to review the research progress of materials for mono-/di-valent ions separation membranes in recent years.It focused on the current status of polymeric membranes,mixed-matrix membranes and novel membranes such as metal-organic frameworks and twodimensional-materials for mono-/di-valent ions separation;the effect of fabrication methods such as interfacial polymerization,layer-by-layer,deposition and blending on the membrane structures and separation performance;the main challenges and future research directions of mono-/di-valent ions separation membranes.

关 键 词：膜 分离 选择性 一/二价离子 离子筛分 

分 类 号：TQ028[化学工程]