铝-氟聚物反应性物质制备及研究进展  

Preparation and Research Progress of Aluminum-fluoropolymer Reactive Materials

作　　者：王靖岩 王义智 韩志伟[1] WANG Jing-yan;WANG Yi-zhi;HAN Zhi-wei(School of Chemistry Engineering,Nanjing University of Science and Technology,Nanjing 210094,China;Nanjing Changshan Chemical Co.,Ltd.,Nanjing 211103,China)

机构地区：[1]南京理工大学化工学院,江苏南京210094 [2]南京长山化工有限责任公司,江苏南京211103

出　　处：《含能材料》2021年第1期78-86,I0005,共10页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金资助(11702142);江苏省自然科学基金资助(BK20170825)。

摘　　要：综述了物理混合法、球磨法、气相沉积法、静电喷雾/纺丝法、溶剂/非溶剂法、3D打印法六大类制备方法,从产品性能、方法的优缺点等角度对近些年来铝-氟聚物反应性物质的研究进展进行简要综述。介绍了铝-氟聚物反应性物质在慢升温速率和快升温速率下的反应过程。指出今后研究的重点方向为:设计一种能集各种制备方法优点于一身的新方法,加强铝-氟聚物反应性物质受热时氟聚物和铝的反应机理的研究。Six preparation methods of physical mixing,ball milling,vapor deposition,electrostatic spray/spinning,solvent/non-solvent and 3D printing for aluminum-fluoro reactive materials are summarized.Recent research progress of Al-fluoropolymer reactive materials are reviewed from the aspect of product performance and method advantages and disadvantages.The reaction process of aluminum-fluoropolymer reactive materials at slow heating rate and fast heating rate are introduced.The promising research directions in the future are pointed out,including design a new method that combines the advantages of various preparation methods and more attention should be paid to strengthen the research on the reaction mechanism of aluminum-fluo ropolymer reactive materials when heated.

关 键 词：铝粉 氟聚物 反应性物质 制备方法 反应过程 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术]