重质油悬浮床加氢技术和相关催化剂的研究进展  

Research progress on residue slurry-bed hydrogenation technology and related catalysts

作　　者：吴孟德 李广慈 李明时[1] 李学兵[2] 庄庆发 陈松 Wu Mengde;Li Guangci;Li Mingshi;Li Xuebing;Zhuang Qingfa;Chen Song(School of Petrochemical Engineering,Changzhou University,Changzhou 213164,Jiangsu China;Qingdao Institute of Bioenergy and Bioprocess Technology,Chinese Academy of Sciences,Qingdao 266101,Shandong,China)

机构地区：[1]常州大学石油化工学院,江苏常州213164 [2]中国科学院青岛生物能源与过程研究所,山东青岛266101

出　　处：《工业催化》2020年第12期1-11,共11页Industrial Catalysis

基　　金：国家自然科学基金(21761132006);重质油国家重点实验室开放基金资助项目(2018-02);青岛能源所科研创新基金项目和中国科学院洁净能源创新研究所资助项目(QIBEBTl201933)。

摘　　要：悬浮床加氢技术旨在劣质油品的加氢处理和生产清洁燃料,实现能源的充分利用,缓解能源危机和降低环境污染。围绕悬浮床加氢技术及相关催化剂进行展开,针对VCC悬浮床加氢技术、EST减压渣油悬浮床加氢技术、UPC重质油悬浮床加氢技术、UniflexSHC悬浮床加氢制备低硫轻质油技术、悬浮床加氢HDH-PLUS技术、悬浮床加氢尾油循环技术、悬浮床煤油共炼加氢技术,评述各类技术的特点与发展趋势,并对固体颗粒催化剂、水溶性催化剂、油溶性催化剂、微乳型催化剂等几类常用的悬浮床加氢催化剂进行详细的分析与总结。悬浮床加氢技术在超稠油、减压渣油等劣质油品的加工、处理方面前景广阔。Slurry-bed catalytic hydrogenation process is aimed at hydroprocessing of inferior oil and producing clean fuels,in order to improve the utilization of energy,alleviate energy crisis,and reduce environmental pollution.In this paper,various slurry-bed hydrogenation technologies and related catalysts are reviewed,and the characteristics and development trends of those technologies,such as VCC slurry-bed hydrogenation,EST vacuum residue hydrocracking,UPC heavy oil slurry-bed hydrogenation,UniflexSHC slurry-bed hydrogenation,HDH-PLUS slurry-bed hydrogenation for tail oil recycling process,and slurry-bed coal-oil hydrocracking process,are discussed.Moreover,different types of commonly used catalysts in slurry-bed hydrogenation processes,including solid particle catalysts,water-soluble catalysts,oil-soluble catalysts,and microemulsion catalysts,are analyzed and summarized in detail.Slurry-bed catalytic hydrogenation technology has broad prospects on the processing and treatment of super heavy oil and vacuum residue in the future.

关 键 词：石油化学工程 劣质油品 清洁燃料 悬浮床加氢技术 加氢催化剂 超稠油 减压渣油 

分 类 号：TE624.43[石油与天然气工程—油气加工工程] TQ426.95[化学工程]