增强热塑性塑料管材高温水浴老化性能研究  

Research on Aging Performance of Reinforced Thermoplastic Pipe(RTP)in High Temperature Water Bath

作　　者：刘德俊 张阿昱 刘亚明[1,2] 梁航 孙文盛[1,2] 赵苗苗 LIU De-jun;ZHANG A-yu;LIU Ya-ming;LIANG Hang;SUN Wen-sheng;ZHAO Miao-miao(National Petroleum and Gas Tubular Goods Engineering Research Center,Baoji 721008,China;Baoji Petroleum Steel Pipe Co.,Ltd.,Baoji 721008,China)

机构地区：[1]国家石油天然气管材工程技术研究中心,陕西宝鸡721008 [2]宝鸡石油钢管有限责任公司,陕西宝鸡721008

出　　处：《塑料工业》2021年第1期98-101,共4页China Plastics Industry

摘　　要：老化易使高分子链断裂,使材料变脆、脱层、变色,严重制约了塑料管材在高温、高湿工况下的应用。以交联聚乙烯PEX、耐热聚乙烯PE-RT和高密度聚乙烯PE100为研究对象,进行90℃水浴老化。采用万能力学试验机、差示扫描量热仪、维卡软化温度测定仪研究了三种材料老化前后力学性能变化和耐热行为。结果表明,在90℃热水浴老化90 d后,PE-RT、PE100、PEX的力学性能和耐热性能都出现下降趋势,其中交联聚乙烯PEX老化后力学性能和耐热行为保持最好,拉伸强度大于20 MPa、维卡软化温度高于85℃,220℃氧化诱导时间大于20 min,可以作为耐高温非金属复合管备选内衬材料。Aging was easy to cause the polymer chain fracture.And the materials could become brittle,delaminating and discoloration,which severely restricted the use of plastic pipe materials under high temperature and high humidity conditions.In this study,cross-linked polyethylene PEX,heat-resistant polyethylene PE-RT and high-density polyethylene PE100 were aged in a high-temperature water bath at 90℃.Electronic universal testing machine,differential scanning calorimeter,and the Vicat softening point temperature tester were used to study the changes in mechanical properties and heat-resistant deformation before and after aging.The results show that after 90 days of aging at 90℃,the mechanical properties and heat resistance of PE-RT,PE100 and PEX all have a decline trend.Among them,the cross-linked polyethylene PEX has the best tensile properties and heat resistance properties.Its tensile strength is more than 20 MPa,the Vicat softening point temperature is higher than 85℃,and oxidation induction time(OIT)at 220℃is longer than 20 min.It can be used as an alternative lining material for high temperature resistant non-metal composite pipes.

关 键 词：管材原料 老化 高温水浴 拉伸性能 耐热性能 

分 类 号：TQ325.12[化学工程—合成树脂塑料工业]