催化氨硼烷水解制氢研究进展  

Recent Advances in Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane

作　　者：刘军辉[1] 郭旭明[1] 宋亚坤 郭新闻[2] LIU Jun-Hui;GUO Xu-Ming;SONG Ya-Kun;GUO Xin-Wen(College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang 471023,China;State Key Laboratory of Fine Chemicals,PSU-DUT Joint Center for Energy Research,School of Chemical Engineering,Dalian University of Technology,Dalian 116024,China)

机构地区：[1]河南科技大学化工与制药学院,洛阳471023 [2]大连理工大学化工学院,宾州-大连联合能源研究中心,精细化工国家重点实验室,大连116024

出　　处：《应用化学》2021年第2期157-169,共13页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(No.21908043);河南省重点攻关项目(No.192102310209)项目资助。

摘　　要：当前,世界范围内的能源利用面临着巨大的挑战,开发绿色洁净能源十分重要。通过水解氨硼烷制备清洁可再生的氢气是解决能源问题的有效途径之一。选择合适的催化剂有效提高制氢效率是氨硼烷水解制氢的关键,开发高效安全的催化剂一直是该领域研究的重点和热点。本文从影响氨硼烷水解制氢反应中催化剂催化性能的因素出发,综述了活性金属组分和载体在催化剂制备过程中以及催化氨硼烷制氢反应中的作用。最后,对催化氨硼烷水解制氢过程所存在的问题以及今后的发展进行了总结和展望。Energy utilization in the world is facing great challenges and it is very important to develop green and clean energy.Hydrolysis of ammonia borane is one of the effective routes to produce clean and renewable hydrogen and suitable catalysts can improve the efficiency of hydrogen production in the hydrolysis reaction.The development of efficient and safe catalysts has been the focus and hotspot in this field.This paper reviews the role of active metal components and supports in the preparation of catalysts and the catalytic hydrolysis of ammonia borane based on the key factors that affect the catalytic performance.Finally,the current problems are summarized and the future development of this field is pointed out.

关 键 词：制氢 氨硼烷 催化剂 活性组分 载体 

分 类 号：O643.3[理学—物理化学]